Arid
DOI10.3390/polym16121756
Study on Adsorption Characteristics and Water Retention Properties of Attapulgite-Sodium Polyacrylate and Polyacrylamide to Trace Metal Cadmium Ion
Cai, Ziming; Zhan, Feng; Wang, Yingnan; Wu, Meiling; Kong, Lingjian; Wang, An; Huang, Zhanbin
通讯作者Zhan, F
来源期刊POLYMERS
EISSN2073-4360
出版年2024
卷号16期号:12
英文摘要The adsorption mechanism of superabsorbent polymer (SAP) can provide theoretical guidance for their practical applications in different environments. However, there has been limited research on the mechanism of attapulgite-sodium polyacrylate. This research aimed to compare the Cd(II) adsorption characteristics and water retention properties of organic-inorganic composite SAP (attapulgite-sodium polyacrylate, OSAP) and organic SAP (polyacrylamide, JSAP). Batch experiments were used to investigate the kinetics of Cd(II) adsorption, as well as the thermodynamic properties and factors influencing these properties. The results show that the Cd(II) adsorption capacity was directly proportional to the pH value. The maximum adsorption capacities of OSAP and JSAP were of 770 and 345 mgg(-1). The Cd(II) adsorption for OSAP and JSAP conformed to the Langmuir and the quasi-second-order kinetic model. This indicates that chemical adsorption is the primary mechanism. The adsorption process was endothermic (Delta H0 > 0) and spontaneous (Delta G0 < 0). The water adsorption ratios of OSAP and SAP were 474.8 and 152.6 in pure water. The ratio decreases with the increase in Cd(II) concentration. OSAP and JSAP retained 67.23% and 38.37% of the initial water adsorption after six iterations of water adsorption. Hence, OSAP is more suitable than JSAP for agricultural and environmental ecological restoration in arid and semi-arid regions.
英文关键词superabsorbent polymer cadmium ion (Cd(II)) adsorption capacity adsorption kinetics water adsorption ratio
类型Article
语种英语
开放获取类型gold
收录类别SCI-E
WOS记录号WOS:001257341600001
WOS关键词ACTIVATED CARBON ; INFRARED SPECTRA ; AQUEOUS-SOLUTION ; HEAVY-METALS ; REMOVAL ; ACID ; WASTEWATERS ; COMPOSITE ; SORPTION ; SINGLE
WOS类目Polymer Science
WOS研究方向Polymer Science
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/405216
推荐引用方式
GB/T 7714
Cai, Ziming,Zhan, Feng,Wang, Yingnan,et al. Study on Adsorption Characteristics and Water Retention Properties of Attapulgite-Sodium Polyacrylate and Polyacrylamide to Trace Metal Cadmium Ion[J],2024,16(12).
APA Cai, Ziming.,Zhan, Feng.,Wang, Yingnan.,Wu, Meiling.,Kong, Lingjian.,...&Huang, Zhanbin.(2024).Study on Adsorption Characteristics and Water Retention Properties of Attapulgite-Sodium Polyacrylate and Polyacrylamide to Trace Metal Cadmium Ion.POLYMERS,16(12).
MLA Cai, Ziming,et al."Study on Adsorption Characteristics and Water Retention Properties of Attapulgite-Sodium Polyacrylate and Polyacrylamide to Trace Metal Cadmium Ion".POLYMERS 16.12(2024).
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