Arid
DOI10.1007/s13762-024-05789-0
The adsorption-desorption behavior of 2,4-dichlorophenol on microplastics in waters with different salinity
Liu, S.; Ma, Y.; Liu, H.; Wang, S.
通讯作者Wang, S
来源期刊INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
ISSN1735-1472
EISSN1735-2630
出版年2024
英文摘要Microplastics may play an important role in the migration of contaminants. Meanwhile, drastic changes in water salinity significantly impact adsorption or desorption. The present work investigated the adsorption and desorption of 2,4-dichlorophenol (2,4-DCP) on microplastics in different salinities which were simulated by river water (0.3 parts per thousand), lake water (15 parts per thousand, 35 parts per thousand and 70 parts per thousand) and sea water (15 parts per thousand, 35 parts per thousand and 70 parts per thousand), and was monitored by quartz crystal microbalance (QCM) and batch experiment. Furthermore, ATR-FTIR and Raman's analysis were performed for microplastics before and after adsorption in different water systems, which provided evidence of 2,4-DCP linkage on microplastics. The mass of 2,4-DCP adsorbed on the microplastics showed the highest in river water (0.92 mu g cm-2) and desorbed more and faster in 35 parts per thousand sea-salt water, which means that the most efficient adsorption was achieved in freshwater and slightly decreased in seawater. The influence of salinity on the adsorption of 2,4-DCP may be due to the electrical double layer, and ions from lake and sea salt may also compete for the adsorption sites on the surface of microplastics. The findings of this study will contribute to a deeper understanding of the fate of contaminants adsorbed on microplastics in arid regions and estuary environments, which are subject to rapid changes in salinity.
英文关键词Aquatic ecosystem Microplastic 2,4-DCP Adsorption-desorption Salinity Quartz crystal microbalance
类型Article ; Early Access
语种英语
收录类别SCI-E
WOS记录号WOS:001242501100005
WOS关键词PERSISTENT ORGANIC POLLUTANTS ; PLASTIC DEBRIS ; CONTAMINATED WATER ; AQUEOUS-SOLUTIONS ; REMOVAL ; ACCUMULATION ; SEDIMENTS ; BIODEGRADATION ; ENVIRONMENT ; TRANSPORT
WOS类目Environmental Sciences
WOS研究方向Environmental Sciences & Ecology
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/404237
推荐引用方式
GB/T 7714
Liu, S.,Ma, Y.,Liu, H.,et al. The adsorption-desorption behavior of 2,4-dichlorophenol on microplastics in waters with different salinity[J],2024.
APA Liu, S.,Ma, Y.,Liu, H.,&Wang, S..(2024).The adsorption-desorption behavior of 2,4-dichlorophenol on microplastics in waters with different salinity.INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY.
MLA Liu, S.,et al."The adsorption-desorption behavior of 2,4-dichlorophenol on microplastics in waters with different salinity".INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2024).
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