干旱区生态环境知识资源中心(Arid): 3D printed device coated with solid-phase extraction resin for the on-site extraction of seven sulfonamides from environmental water samples preceding HPLC-DAD analysis

Arid

DOI	10.1016/j.microc.2023.108609
	3D printed device coated with solid-phase extraction resin for the on-site extraction of seven sulfonamides from environmental water samples preceding HPLC-DAD analysis
	Barzallo, Diego; Palacio, Edwin; March, Juan; Ferrer, Laura
通讯作者	Ferrer, L
来源期刊	MICROCHEMICAL JOURNAL
ISSN	0026-265X
EISSN	1095-9149
出版年	2023
卷号	190
英文摘要	A 3D printed device coated with Oasis MCX resin was developed allowing both the on-site and laboratory extraction and pre-concentration of sulfonamides (SAs) and subsequent determination by HPLC with diode array detection (DAD). The device has been designed and printed by stereolithographic 3D printing and functionalized with a SPE resin by stick and cure immobilization technique. Images of 3D printed coated devices obtained by scanning electron microscopy (SEM) allowed its characterization. Various parameters that affect the extraction efficiency (eluent solution, eluent volume, extraction and elution times) were studied and under optimal con-ditions, seven sulfonamides (Sulfanilamide, SAM; Sulfadiazine, SDZ; Sulfamerazine, SMR; Sulfamethazine, SMZ; Sulfamethoxypyridazine, SMP; Sulfamethoxazole, SMX; and Sulfadimethoxine, SDX) have been satisfactorily quantified after the 3D coated-device extraction. Detection limits of 6, 6, 0.9, 0.9, 0.8, 0.7, and 0.6 mu g L-1 were achieved for SAM, SDZ, SMR, SMZ, SMP, SMX, and SDX, respectively. In all cases, a good linearity was observed up to 1000 mu g L-1 with R2 between 0.9987 and 0.9998. The interday precision expressed as relative standard deviation (n = 3) varied between 2.2 and 5.5 % RSD, showing the good precision of the proposed methodology. Finally, the developed method was successfully used for the simultaneous analysis of seven SAs in samples of tap water and wastewater. Therefore, the 3D printed device is an efficient, miniaturized, and simple alternative for monitoring emerging contaminants derived from Pharmaceutical and Personal Care Products such as SAs in environmental water samples.
英文关键词	Portable 3D printed device On-site solid-phase extraction Sulfonamides HPLC-DAD
类型	Article
语种	英语
开放获取类型	hybrid
收录类别	SCI-E
WOS记录号	WOS:000955537900001
WOS关键词	PERFORMANCE LIQUID-CHROMATOGRAPHY ; MASS-SPECTROMETRY ; SURFACE-WATER ; WASTE-WATER ; ANTIBIOTICS ; ELECTROSPRAY ; MICROEXTRACTION ; PRECONCENTRATION ; PHARMACEUTICALS ; QUANTIFICATION
WOS类目	Chemistry, Analytical
WOS研究方向	Chemistry
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/397841
推荐引用方式 GB/T 7714	Barzallo, Diego,Palacio, Edwin,March, Juan,et al. 3D printed device coated with solid-phase extraction resin for the on-site extraction of seven sulfonamides from environmental water samples preceding HPLC-DAD analysis[J],2023,190.
APA	Barzallo, Diego,Palacio, Edwin,March, Juan,&Ferrer, Laura.(2023).3D printed device coated with solid-phase extraction resin for the on-site extraction of seven sulfonamides from environmental water samples preceding HPLC-DAD analysis.MICROCHEMICAL JOURNAL,190.
MLA	Barzallo, Diego,et al."3D printed device coated with solid-phase extraction resin for the on-site extraction of seven sulfonamides from environmental water samples preceding HPLC-DAD analysis".MICROCHEMICAL JOURNAL 190(2023).