干旱区生态环境知识资源中心(Arid): Rapid Determination of Five Kinds of Emerging Mycotoxins in Fruit and Vegetable Products by PRIME HLB Purification Coupled with Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry

Arid

DOI	10.19756/j.issn.0253-3820.221478
	Rapid Determination of Five Kinds of Emerging Mycotoxins in Fruit and Vegetable Products by PRIME HLB Purification Coupled with Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry
	Zhang, Dan; Liu, Bo-Lin; Zhao, Zi-Wei; Zhan, Zi-Yue; Xie, Ji-An; Li, Wei-Dong
通讯作者	Liu, BL ; Li, WD
来源期刊	CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
ISSN	0253-3820
EISSN	1872-2040
出版年	2023
卷号	51 期号:8 页码:1343-1352
英文摘要	An analytical strategy for simultaneous and rapid determination of five kinds of emerging mycotoxins, including beauvericin, enniatin a, enniatin al, enniatin b and enniatin b1 in fruit and vegetable products by ultra-high performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) was developed. The homogenized samples were extracted by acetonitrile aqueous solution or acetonitrile (containing 1.0% acetic acid), and purified by Oasis PRiME HLB solid phase extraction column. The extraction conditions and detection parameters were optimized. The results showed that the five kinds of emerging mycotoxins had good linear relationships in their respective concentration ranges, and the correlation coefficients (r2) ranged from 0.9988 to 0.9998. The limits of detection (LOD) were 0.005-0.025 & mu;g/kg, and the limits of quantification (LOQ) were 0.017-0.080 & mu;g/kg. Good recoveries (86.7%-117.8%) and a relative standard deviation (RSD) less than 18.4% were obtained from 9 liquid and 12 solid samples spiked with three levels of mycotoxins (0.25, 2.50 and 10.00 & mu;g/kg), which showed that the accuracy of the method developed here was satisfied. A total of 100 samples of fruit and vegetable products were detected using the established method, and the results showed that the detection rate of five kinds of emerging mycotoxins was 35%-66%, and the maximum concentration was 2.96 & mu;g/kg. Overall, the sample pretreatment was quite simple, and the detection method had high sensitivity and good stability, and could realize accurate quantification, which was suitable for the simultaneous and rapid determination of mycotoxins in fruit and vegetable products.
英文关键词	Ultra-high performance liquid chromatography-tandem mass spectrometry Emerging mycotoxin Beauvericin Enniatins
类型	Article
语种	中文
收录类别	SCI-E
WOS记录号	WOS:001065417300001
WOS关键词	FUSARIUM MYCOTOXINS ; BEAUVERICIN ; ENNIATINS ; SAMPLES ; FEED ; B1 ; A1
WOS类目	Chemistry, Analytical
WOS研究方向	Chemistry
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/395753
推荐引用方式 GB/T 7714	Zhang, Dan,Liu, Bo-Lin,Zhao, Zi-Wei,et al. Rapid Determination of Five Kinds of Emerging Mycotoxins in Fruit and Vegetable Products by PRIME HLB Purification Coupled with Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry[J],2023,51(8):1343-1352.
APA	Zhang, Dan,Liu, Bo-Lin,Zhao, Zi-Wei,Zhan, Zi-Yue,Xie, Ji-An,&Li, Wei-Dong.(2023).Rapid Determination of Five Kinds of Emerging Mycotoxins in Fruit and Vegetable Products by PRIME HLB Purification Coupled with Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,51(8),1343-1352.
MLA	Zhang, Dan,et al."Rapid Determination of Five Kinds of Emerging Mycotoxins in Fruit and Vegetable Products by PRIME HLB Purification Coupled with Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 51.8(2023):1343-1352.