干旱区生态环境知识资源中心(Arid): An efficient mixed-mode strong anion-exchange adsorbent based on functionalized polyethyleneimine for simultaneous solid phase extraction and purification of bisphenol analogues and monoalkyl phthalate esters in human urine

Arid

DOI	10.1016/j.microc.2022.107536
	An efficient mixed-mode strong anion-exchange adsorbent based on functionalized polyethyleneimine for simultaneous solid phase extraction and purification of bisphenol analogues and monoalkyl phthalate esters in human urine
	Huang, Chaonan; Yang, Jiajia; Ma, Jiping; Tan, Weiqiang; Wu, Lingxia; Shan, Bin; Wang, Shasha; Chen, Jiping; Li, Yun
通讯作者	Huang, CA
来源期刊	MICROCHEMICAL JOURNAL
ISSN	0026-265X
EISSN	1095-9149
出版年	2022
卷号	180
英文摘要	In this study, a mixed-mode strong anion-exchange (MAX) adsorbent was developed based on amine-functionalized poly(divinylbenzene) (PDVB) functionalized with polyethyleneimine (PEI) followed by quaternization with glycidyl phenyl ether (named as PDVB-QPEI). Fourier Transform Infrared spectroscopy and nitrogen adsorption-desorption experiments indicated that the PDVB-QPEI was successfully synthesized with a BET specific surface area (S-BET) of 118.5 m(2) g(- 1), pore volume of 0.37 cm(3 )g(-1), and pore size of 16.41 nm. High ion-exchange capacity (IEC) of 0.57 mmol g(-1) was achieved. The important parameters influencing SPE efficiency were optimized, including adsorbent mass, pH of the sample, type and volume of washing solvent and eluent. The practical capability of this novel PDVB-QPEI MAX adsorbent was tested for solid phase extraction and purification of bisphenol analogues and monoalkyl phthalate esters (MPEs) in urine samples. Outstanding extraction and cleanup efficiency were achieved simultaneously for urine samples due to high selectivity of the PDVB-QPEI adsorbent for bisphenol analogues and MPEs. Recovery values ranged from 80.1% to 102.4% with precision (relative standard devition, n = 3) below 6% for these blank urine samples spiked at different levels. The limit of detections (LODs) obtained by HPLC-DAD were in the range of 3-9 ng mL(-1). The PDVB-QPEI is superior to commercial adsorbents (Oasis HLB, C18 and Oasis MAX). These results demonstrated the great potential application of the PDVB-QPEI adsorbent in routine analysis of bisphenol analogues and MPEs in complex samples.
英文关键词	Polyethyleneimine Mixed -mode strong anion-exchange adsorbent Solid phase extraction Endocrine disrupting chemical Urine sample
类型	Article
语种	英语
收录类别	SCI-E
WOS记录号	WOS:000804064900006
WOS关键词	ACIDIC PHARMACEUTICALS ; PHENOLIC-COMPOUNDS ; MASS-SPECTROMETRY ; CHROMATOGRAPHY ; SORBENT ; MS/MS ; MILK
WOS类目	Chemistry, Analytical
WOS研究方向	Chemistry
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/393792
推荐引用方式 GB/T 7714	Huang, Chaonan,Yang, Jiajia,Ma, Jiping,et al. An efficient mixed-mode strong anion-exchange adsorbent based on functionalized polyethyleneimine for simultaneous solid phase extraction and purification of bisphenol analogues and monoalkyl phthalate esters in human urine[J],2022,180.
APA	Huang, Chaonan.,Yang, Jiajia.,Ma, Jiping.,Tan, Weiqiang.,Wu, Lingxia.,...&Li, Yun.(2022).An efficient mixed-mode strong anion-exchange adsorbent based on functionalized polyethyleneimine for simultaneous solid phase extraction and purification of bisphenol analogues and monoalkyl phthalate esters in human urine.MICROCHEMICAL JOURNAL,180.
MLA	Huang, Chaonan,et al."An efficient mixed-mode strong anion-exchange adsorbent based on functionalized polyethyleneimine for simultaneous solid phase extraction and purification of bisphenol analogues and monoalkyl phthalate esters in human urine".MICROCHEMICAL JOURNAL 180(2022).