干旱区生态环境知识资源中心(Arid): Preparation and application of polystyrene-divinylbenzene sorbent with weak cation-exchange character for the selective extraction of illicit drugs in environmental water

Arid

DOI	10.1016/j.chroma.2022.462994
	Preparation and application of polystyrene-divinylbenzene sorbent with weak cation-exchange character for the selective extraction of illicit drugs in environmental water
	Ning, Hongyu; Fan, Yilei; Liu, Huijun; Huang, Zhongping; Ke, Xing; Xu, Yu; She, Yuanbin
通讯作者	Huang, ZP
来源期刊	JOURNAL OF CHROMATOGRAPHY A
ISSN	0021-9673
EISSN	1873-3778
出版年	2022
卷号	1671
英文摘要	A B S T R A C T A novel mixed-mode weak cation-exchange sorbent (PS-DVB-WCX-II) was prepared by the modification of polystyrene-divinylbenzene with mercaptosuccinic acid for the selective extraction of illicit drugs in environmental water. The PS-DVB-WCX-II was synthesized through the Friedel-Crafts acylation reaction on the surface of polystyrene-divinylbenzene, followed by nucleophilic substitution reaction and thiolene click reaction. The sorbent can selectively absorb illicit drugs through the reverse-phase interactions provided by benzene ring on the polymer backbone and the ion-exchange interactions provided by functional group (-COOH). As compared with the extraction performance of three commercial SPE cartridges, it was found that the prepared sorbent had better adsorption performance with the recovery values between 84.1% and 106.0% for the selected 11 illicit drugs under the optimized SPE conditions. Illicit drugs in environmental water were extracted by the sorbent, prior to the detection of UHPLC-MS/MS. Two quantitative methods were established respectively for the detection of 11 illicit drugs in different matrices of river water and wastewater. Both methods had good determination coefficient (r 2 > 0.992) in the range of 0.5-50 ng/L, 2.5-250 ng/L, 5-500 ng/L, and low limits of detection (S/N = 3) of 0.17-1.67 ng/L. In the real wastewater samples, the concentration of morphine was 18.3-126.3 ng/L, and the methamphetamine was 12.7-27.4 ng/L. Meanwhile, PS-DVB-WCX-II was compared with Oasis MCX and Oasis HLB in the detection of real wastewater samples. The results revealed that PS-DVB-WCX-II and Oasis MCX had better performance in absorbing methamphetamine than Oasis HLB, and PS-DVB-WCX-II had better ability to remove the matrix. The results suggested that the prepared weak cation-exchange sorbent had the potential in the application of illicit drug detection in environmental water.(c) 2022 Elsevier B.V. All rights reserved.
英文关键词	Mixed-mode weak cation-exchange sorbent Solid-phase extraction Illicit drugs Environmental water
类型	Article
语种	英语
收录类别	SCI-E
WOS记录号	WOS:000790442600003
WOS关键词	SOLID-PHASE EXTRACTION ; RESOLUTION MASS-SPECTROMETRY ; LIQUID-CHROMATOGRAPHY ; WASTE-WATER ; RESIDUE ANALYSIS ; METABOLITES ; PHARMACEUTICALS ; METHAMPHETAMINE ; AMPHETAMINE ; WASTEWATERS
WOS类目	Biochemical Research Methods ; Chemistry, Analytical
WOS研究方向	Biochemistry & Molecular Biology ; Chemistry
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/393358
推荐引用方式 GB/T 7714	Ning, Hongyu,Fan, Yilei,Liu, Huijun,et al. Preparation and application of polystyrene-divinylbenzene sorbent with weak cation-exchange character for the selective extraction of illicit drugs in environmental water[J],2022,1671.
APA	Ning, Hongyu.,Fan, Yilei.,Liu, Huijun.,Huang, Zhongping.,Ke, Xing.,...&She, Yuanbin.(2022).Preparation and application of polystyrene-divinylbenzene sorbent with weak cation-exchange character for the selective extraction of illicit drugs in environmental water.JOURNAL OF CHROMATOGRAPHY A,1671.
MLA	Ning, Hongyu,et al."Preparation and application of polystyrene-divinylbenzene sorbent with weak cation-exchange character for the selective extraction of illicit drugs in environmental water".JOURNAL OF CHROMATOGRAPHY A 1671(2022).