Arid
DOI10.1007/s10040-022-02562-w
Natural occurrence and controls of arsenic in groundwater in a semiarid basin in the Mexican Altiplano
Cauich-Kau, Dario; Ruede, Thomas R.; Cardona-Benavides, Antonio; Castro-Larragoitia, Javier
通讯作者Cauich-Kau, D
来源期刊HYDROGEOLOGY JOURNAL
ISSN1431-2174
EISSN1435-0157
出版年2022
卷号30期号:8页码:2459-2477
英文摘要The sources, mobility, and controlling processes of arsenic (As) in an aquifer system in the Cerritos-Guadalcazar area of Central Mexico were investigated. High As concentrations (up to 128 mu g/L) in groundwater were found to be associated with both primary sources (rocks and tailings) and secondary sources (soil and sediments). The high As concentrations in the otherwise pristine Cerritos shallow granular aquifer are the result of a distant source of As-rich sediments eroded from a mineralized area in the recharge zone of a karstic aquifer. An intermediate groundwater flow system delivers the As load from the karstic to the granular aquifer. In addition, identification of a Na-Cl water type in the shallow granular aquifer indicates a regional flow; however, additional information is needed to corroborate this assumption. Local flows in the karstic aquifer are Ca-HCO3 water type with low (<1 mu g/L) dissolved As concentrations. Principle axis factor analysis shows distinct groupings associated with different aquifer characteristics. The sulfate factor dominates in the southern area of the granular aquifer, which explains 30% of the total variance. The arsenic-uranium factor is expressed in samples from deep and dug wells tapping the basin sediments. A conceptual model was developed where the path of the As is shown. Three groups of samples showed negative correlation among deuterium excess and As concentrations. Evaporation modeling to simulate the As enrichment showed that evaporation processes play an important role in As behavior. This research can provide a tool for further studies in the Sierra Madre Oriental.
英文关键词Arsenic Arid regions Groundwater monitoring Hydrochemistry Mexico
类型Article
语种英语
开放获取类型hybrid
收录类别SCI-E
WOS记录号WOS:000883222100002
WOS关键词TRACE-ELEMENTS ; LATIN-AMERICA ; FLUORIDE ; ENRICHMENT ; ISOTOPES ; GENESIS ; CHILE
WOS类目Geosciences, Multidisciplinary ; Water Resources
WOS研究方向Geology ; Water Resources
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/393040
推荐引用方式
GB/T 7714
Cauich-Kau, Dario,Ruede, Thomas R.,Cardona-Benavides, Antonio,et al. Natural occurrence and controls of arsenic in groundwater in a semiarid basin in the Mexican Altiplano[J],2022,30(8):2459-2477.
APA Cauich-Kau, Dario,Ruede, Thomas R.,Cardona-Benavides, Antonio,&Castro-Larragoitia, Javier.(2022).Natural occurrence and controls of arsenic in groundwater in a semiarid basin in the Mexican Altiplano.HYDROGEOLOGY JOURNAL,30(8),2459-2477.
MLA Cauich-Kau, Dario,et al."Natural occurrence and controls of arsenic in groundwater in a semiarid basin in the Mexican Altiplano".HYDROGEOLOGY JOURNAL 30.8(2022):2459-2477.
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