Arid
DOI10.1007/s10040-022-02450-3
Isotopic and geochemical tracers of groundwater flow in the Shivwits Plateau, Grand Canyon National Park, USA
Wilson, Jonathan W.; Erhardt, Andrea M.; Tobin, Benjamin W.
Corresponding AuthorWilson, JW (corresponding author),Univ Kentucky, Dept Earth & Environm Sci, Lexington, KY 40506 USA.
JournalHYDROGEOLOGY JOURNAL
ISSN1431-2174
EISSN1435-0157
Year Published2022-02
Abstract in EnglishUnderstanding patterns of groundwater flow are important when quantifying and mitigating threats to critical groundwater resources. Environmental tracers, determined from discrete sampling, could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. This study explores the novel inclusion of delta C-13 of dissolved organic carbon (DOC), delta C-13 of dissolved inorganic carbon (DIC) and fluorescent dissolved organic matter (fDOM), along with more commonly used multi-tracer approaches that involve water isotopes, major ions, and saturation indices, to characterize springs of the Shivwits Plateau in Grand Canyon National Park, USA. Carbon isotope ratios and fDOM concentrations for all springs reflect source values associated with regional surface vegetation and heterotrophic degradation of terrestrial DOM. Principal component analyses show that springs can be grouped by geochemical variability into: (1) a shallow epikarst system, (2) a flow path through gypsiferous beds of the Toroweap Formation on the eastern side of the plateau, (3) a short canyon-slope flow path dominated by runoff, and (4) a deeper complex flow system in the Redwall Limestone characteristic of mixing of all other flow systems. As appropriations from the Colorado River already exceed its annual streamflow, characterizing groundwater resources for water supply in an increasingly arid climate will be paramount. These results demonstrate the effectiveness of geochemical techniques for groundwater flow characterization, particularly in inaccessible environments.
Keyword in EnglishEnvironmental tracers Stable isotopes Geochemistry USA Springs
SubtypeArticle ; Early Access
Language英语
Indexed BySCI-E
WOS IDWOS:000751591700001
WOS KeywordDISSOLVED ORGANIC-MATTER ; INORGANIC CARBON ; KAIBAB PLATEAU ; FLUORESCENCE SPECTROSCOPY ; STABLE-ISOTOPES ; KARST AQUIFERS ; CLIMATE-CHANGE ; LONG-TERM ; WATER ; SOIL
WOS SubjectGeosciences, Multidisciplinary ; Water Resources
WOS Research AreaGeology ; Water Resources
Document Type期刊论文
Identifierhttp://119.78.100.177/qdio/handle/2XILL650/377339
Affiliation[Wilson, Jonathan W.; Erhardt, Andrea M.] Univ Kentucky, Dept Earth & Environm Sci, Lexington, KY 40506 USA; [Tobin, Benjamin W.] Univ Kentucky, Kentucky Geol Survey, Lexington, KY 40506 USA
Recommended Citation
GB/T 7714
Wilson, Jonathan W.,Erhardt, Andrea M.,Tobin, Benjamin W.. Isotopic and geochemical tracers of groundwater flow in the Shivwits Plateau, Grand Canyon National Park, USA[J],2022.
APA Wilson, Jonathan W.,Erhardt, Andrea M.,&Tobin, Benjamin W..(2022).Isotopic and geochemical tracers of groundwater flow in the Shivwits Plateau, Grand Canyon National Park, USA.HYDROGEOLOGY JOURNAL.
MLA Wilson, Jonathan W.,et al."Isotopic and geochemical tracers of groundwater flow in the Shivwits Plateau, Grand Canyon National Park, USA".HYDROGEOLOGY JOURNAL (2022).
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