干旱区生态环境知识资源中心(Arid): Analysis of the Three-Dimensional Fluorescence Spectroscopy Characteristics of Dissolved Organic Matter in Groundwater from a Subtropical Cave in Dry Season-Daxiao Cave in South China Karst

Arid

DOI	10.3390/w13243574
	Analysis of the Three-Dimensional Fluorescence Spectroscopy Characteristics of Dissolved Organic Matter in Groundwater from a Subtropical Cave in Dry Season-Daxiao Cave in South China Karst
	Zhang, Renkai; Liu, Ziqi; Xiong, Kangning; Lyu, Xiaoxi; Hu, Chenpeng; Wang, Xinwen; Cheng, Kun
通讯作者	Xiong, KN (corresponding author)，Guizhou Normal Univ, Sch Karst Sci, Guiyang 550001, Peoples R China. ; Xiong, KN (corresponding author)，State Engn Technol Inst Karst Desertificat Contro, Guiyang 550001, Peoples R China.
来源期刊	WATER
EISSN	2073-4441
出版年	2021
卷号	13 期号:24
英文摘要	Groups in dissolved organic matter (DOM) emit fluorescence information at characteristic wavelengths when irradiated by excitation waves, which can reveal the geochemical behavior of dissolved organic matter in the environment and its sources, but there are few relevant studies in cave groundwater systems. In order to investigate the relationship between drip hydrochemistry characteristics and DOM in cave systems after subsurface leakage, in this study, from the perspective of dissolved organic matter in the karst cave water system, the groundwater in the dry season of Daxiao Cave was selected as the research object. Five drip points and one water pool (DX-1, DX-2, DX-3, DX-4, DX-5, and DX-C) in Daxiao Cave were monitored and consecutively sampled for four months. The parallel factor analysis method (PARAFAC), three-dimensional (3D) fluorescence parameters, and excitation-emission matrix fluorescence spectroscopy (EEM), combined with the hydrochemistry characteristics of the drip water and correlation analysis, were used to analyze the 3D fluorescence spectral characteristics of the DOM of the drip water of Daxiao Cave and their influencing factors. The results show that (1) the hydrochemistry type of the drip water in Daxiao Cave was within the Ca-Mg-HCO3 type, and Ca2+, Mg2+, and HCO3- were the dominant ions in Daxiao Cave; (2) the fluorescence fractions of drip water in dry season caves were dominated by C1 (humus-like), C2 (tryptophan-like), and C3 (tyrosine-like), and the fluorescence fractions of drip water DOM were controlled by protein fluorophores; (3) the DOM in the drip water of Daxiao Cave in the dry season was controlled in part by subsurface leakage and was largely the result of microbial degradation; and (4) the DOM of the drip water may be influenced by the chemical composition of the water, but the exact process is not clear.
英文关键词	hydrochemistry DOM cave drip water rocky desertification Daxiao Cave
类型	Article
语种	英语
开放获取类型	gold
收录类别	SCI-E
WOS记录号	WOS:000742395300001
WOS关键词	TRACE-ELEMENT ; EXCITATION ; WATER ; HYDROCHEMISTRY ; SPELEOTHEM ; CHEMISTRY ; MATRIX ; BASIN ; PH ; HUMIFICATION
WOS类目	Environmental Sciences ; Water Resources
WOS研究方向	Environmental Sciences & Ecology ; Water Resources
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/375735
作者单位	[Zhang, Renkai; Liu, Ziqi; Xiong, Kangning; Lyu, Xiaoxi; Hu, Chenpeng; Wang, Xinwen; Cheng, Kun] Guizhou Normal Univ, Sch Karst Sci, Guiyang 550001, Peoples R China; [Zhang, Renkai; Liu, Ziqi; Xiong, Kangning; Lyu, Xiaoxi; Hu, Chenpeng; Wang, Xinwen; Cheng, Kun] State Engn Technol Inst Karst Desertificat Contro, Guiyang 550001, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Renkai,Liu, Ziqi,Xiong, Kangning,et al. Analysis of the Three-Dimensional Fluorescence Spectroscopy Characteristics of Dissolved Organic Matter in Groundwater from a Subtropical Cave in Dry Season-Daxiao Cave in South China Karst[J],2021,13(24).
APA	Zhang, Renkai.,Liu, Ziqi.,Xiong, Kangning.,Lyu, Xiaoxi.,Hu, Chenpeng.,...&Cheng, Kun.(2021).Analysis of the Three-Dimensional Fluorescence Spectroscopy Characteristics of Dissolved Organic Matter in Groundwater from a Subtropical Cave in Dry Season-Daxiao Cave in South China Karst.WATER,13(24).
MLA	Zhang, Renkai,et al."Analysis of the Three-Dimensional Fluorescence Spectroscopy Characteristics of Dissolved Organic Matter in Groundwater from a Subtropical Cave in Dry Season-Daxiao Cave in South China Karst".WATER 13.24(2021).