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DOI	10.2138/am-2021-7766
	Crystal chemistry of schreibersite, (Fe,Ni)(3)P
	Britvin, Sergey N.; Krzhizhanovskaya, Maria G.; Zolotarev, Andrey A.; Gorelova, Liudmila A.; Obolonskaya, Edita, V; Vlasenko, Natalia S.; Shilovskikh, Vladimir V.; Murashko, Mikhail N.
通讯作者	Britvin, SN (corresponding author), St Petersburg State Univ, Inst Earth Sci, Univ Skaya Nab 7-9, St Petersburg 199034, Russia. ; Britvin, SN (corresponding author), Russian Acad Sci, Kola Sci Ctr, Fersman Str 14, Apatity 184209, Russia.
来源期刊	AMERICAN MINERALOGIST
ISSN	0003-004X
EISSN	1945-3027
出版年	2021
卷号	106 期号:9 页码:1520-1529
英文摘要	Schreibersite, (Fe,Ni)(3)P, the most abundant cosmic phosphide, is a principal carrier of phosphorus in the natural Fe-Ni-P system and a likely precursor for prebiotic organophosphorus compounds at the early stages of Earth's evolution. The crystal structure of the mineral contains three metal sites allowing for unrestricted substitution of Fe for Ni. The distribution of these elements across the structure could serve as a tracer of crystallization conditions of schreibersite and its parent celestial bodies. However, discrimination between Fe (Z = 26) and Ni (Z = 28) based on the conventional X-ray structural analysis was for a long time hampered due to the proximity of their atomic scattering factors. We herein show that this problem has been overcome with the implementation of area detectors in the practice of X-ray diffraction. We report on previously unknown site-specific substitution trends in schreibersite structure. The composition of the studied mineral encompasses a Ni content ranging between 0.03 and 1.54 Ni atoms per formula unit (apfu): the entire Fe-dominant side of the join Fe3P-Ni3P. Of 23 schreibersite crystals studied, 22 comprise magmatic and non-magmatic iron meteorites and main group pallasites. The near end-member mineral (0.03 Ni apfu) comes from the pyrometamorphic rocks of the Hatrurim Basin, Negev desert, Israel. It was found that Fe/Ni substitution in schreibersite follows the same trends in all studied meteorites. The dependencies are nonlinear and can be described by second-order polynomials. However, the substitution over the M2 and M3 sites within the most common range of compositions (0.6 < Ni <1.5 apfu) is well approximated by a linear regression: Ni(M2) = 0.84 x Ni(M3) - 0.30 apfu (standard error 0.04 Ni apfu). The analysis of the obtained results shows a strong divergence between the variation of unit-cell parameters of natural schreibersite and those of synthetic (Fe,Ni)(3)P. This indicates that Fe/Ni substitution trends in the mineral and its synthetic surrogates are different. A plausible explanation might be related to the differences in the system equilibration time of meteoritic schreibersite (millions of years) and synthetic (Fe,Ni)(3)P (similar to 100 days). However, regardless of the reason for the observed difference, synthetic (Fe,Ni)(3)P cannot be considered a structural analog of natural schreibersite, and this has to be taken into account when using synthetic (Fe,Ni)(3)P as an imitator of schreibersite in reconstructions of natural processes.
英文关键词	Phosphide schreibersite Fe3P Fe-Ni-P system meteorite planetary interiors crystal structure solid solution
类型	Article
语种	英语
收录类别	SCI-E
WOS记录号	WOS:000715841700009
WOS关键词	HIGH-PRESSURE ; SIKHOTE-ALIN ; X-RAY ; PHOSPHORUS ; METEORITES ; MINERALOGY ; BARRINGERITE ; REFINEMENT ; PHOSPHIDE ; ORIGIN
WOS类目	Geochemistry & Geophysics ; Mineralogy
WOS研究方向	Geochemistry & Geophysics ; Mineralogy
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/368024
作者单位	[Britvin, Sergey N.; Krzhizhanovskaya, Maria G.; Zolotarev, Andrey A.; Gorelova, Liudmila A.; Murashko, Mikhail N.] St Petersburg State Univ, Inst Earth Sci, Univ Skaya Nab 7-9, St Petersburg 199034, Russia; [Britvin, Sergey N.] Russian Acad Sci, Kola Sci Ctr, Fersman Str 14, Apatity 184209, Russia; [Obolonskaya, Edita, V] St Petersburg Min Univ, Min Museum, 2,21st Line, St Petersburg 199106, Russia; [Vlasenko, Natalia S.; Shilovskikh, Vladimir V.] St Petersburg State Univ, Ctr Geoenvironm Res & Modelling, Ulyanovskaya Ul 1, St Petersburg 198504, Russia; [Shilovskikh, Vladimir V.] Russian Acad Sci, Inst Mineral, Urals Branch, Miass 456317, Russia
推荐引用方式 GB/T 7714	Britvin, Sergey N.,Krzhizhanovskaya, Maria G.,Zolotarev, Andrey A.,et al. Crystal chemistry of schreibersite, (Fe,Ni)(3)P[J],2021,106(9):1520-1529.
APA	Britvin, Sergey N..,Krzhizhanovskaya, Maria G..,Zolotarev, Andrey A..,Gorelova, Liudmila A..,Obolonskaya, Edita, V.,...&Murashko, Mikhail N..(2021).Crystal chemistry of schreibersite, (Fe,Ni)(3)P.AMERICAN MINERALOGIST,106(9),1520-1529.
MLA	Britvin, Sergey N.,et al."Crystal chemistry of schreibersite, (Fe,Ni)(3)P".AMERICAN MINERALOGIST 106.9(2021):1520-1529.