Arid
DOI10.1016/j.jenvman.2021.112899
Metal(loid)s remobilization and mineralogical transformations in smelter-polluted savanna soils under simulated wildfire conditions
Tuhy, Marek; Ettler, Vojtech; Rohovec, Jan; Matouskova, Sarka; Mihaljevic, Martin; Kribek, Bohdan; Mapani, Ben
通讯作者Tuhy, M ; Ettler, V (corresponding author), Charles Univ Prague, Inst Geochem Mineral & Mineral Resources, Fac Sci, Albertov 6, Prague 12800 2, Czech Republic.
来源期刊JOURNAL OF ENVIRONMENTAL MANAGEMENT
ISSN0301-4797
EISSN1095-8630
出版年2021
卷号293
英文摘要The surroundings of mines and smelters may be exposed to wildfires, especially in semi-arid areas. The temperature-dependent releases of metal(loid)s (As, Cd, Cu, Pb, Zn) from biomass-rich savanna soils collected near a Cu smelter in Namibia have been studied under simulated wildfire conditions. Laboratory single-step combustion experiments (250-850 degrees C) and experiments with a continuous temperature increase (25-750 degrees C) were coupled with mineralogical investigations of the soils, ashes, and aerosols. Metals (Cd, Cu, Pb, Zn) were released at 500 degrees C, As was successively released via the transformation of As-bearing hydrous ferric oxides, arsenolite (As2O3) grains attached to the organic matter fragments, metal arsenates, and/or As-bearing apatite, followed by the thermal decomposition of enargite (Cu3AsS4) at 500 degrees C. The results indicate that the active and abandoned mining and smelting sites, especially those highly enriched in As, should be protected against wildfires, which can be responsible for substantial As re-emissions.
英文关键词Wildfire Soil Metal(loid)s Remobilization Smelter pollution
类型Article
语种英语
收录类别SCI-E
WOS记录号WOS:000677980900002
WOS关键词THERMAL-DECOMPOSITION ; MERCURY EMISSIONS ; ENVIRONMENTAL STABILITY ; ARSENIC TRANSFORMATION ; PRESCRIBED FIRE ; TSUMEB SMELTER ; TRACE-ELEMENTS ; LEAD ; MOBILIZATION ; BEHAVIOR
WOS类目Environmental Sciences
WOS研究方向Environmental Sciences & Ecology
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/363844
作者单位[Tuhy, Marek; Ettler, Vojtech; Mihaljevic, Martin] Charles Univ Prague, Inst Geochem Mineral & Mineral Resources, Fac Sci, Albertov 6, Prague 12800 2, Czech Republic; [Rohovec, Jan; Matouskova, Sarka] Acad Sci Czech Republ, Inst Geol, Rozvojova 269, Prague 16500 6, Czech Republic; [Kribek, Bohdan] Czech Geol Survey, Geologicka 6, Prague 15200 5, Czech Republic; [Mapani, Ben] Namibia Univ Sci & Technol, Dept Min & Proc Engn, Fac Engn, Private Bag, Windhoek 13388, Namibia
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Tuhy, Marek,Ettler, Vojtech,Rohovec, Jan,et al. Metal(loid)s remobilization and mineralogical transformations in smelter-polluted savanna soils under simulated wildfire conditions[J],2021,293.
APA Tuhy, Marek.,Ettler, Vojtech.,Rohovec, Jan.,Matouskova, Sarka.,Mihaljevic, Martin.,...&Mapani, Ben.(2021).Metal(loid)s remobilization and mineralogical transformations in smelter-polluted savanna soils under simulated wildfire conditions.JOURNAL OF ENVIRONMENTAL MANAGEMENT,293.
MLA Tuhy, Marek,et al."Metal(loid)s remobilization and mineralogical transformations in smelter-polluted savanna soils under simulated wildfire conditions".JOURNAL OF ENVIRONMENTAL MANAGEMENT 293(2021).
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