干旱区生态环境知识资源中心(Arid): Green Synthesis of Flower-Shaped Copper Oxide and Nickel Oxide Nanoparticles via Capparis decidua Leaf Extract for Synergic Adsorption-Photocatalytic Degradation of Pesticides

Arid

DOI	10.3390/catal11070806
	Green Synthesis of Flower-Shaped Copper Oxide and Nickel Oxide Nanoparticles via Capparis decidua Leaf Extract for Synergic Adsorption-Photocatalytic Degradation of Pesticides
	Iqbal, Amna; ul Haq, Atta; Cerron-Calle, Gabriel Antonio; Naqvi, Syed Ali Raza; Westerhoff, Paul; Garcia-Segura, Sergi
通讯作者	Garcia-Segura, S (corresponding author), Arizona State Univ, Nanosyst Engn Res Ctr Nanotechnol Enabled Water T, Sch Sustainable Engn & Built Environm, Tempe, AZ 85287 USA.
来源期刊	CATALYSTS
EISSN	2073-4344
出版年	2021
卷号	11 期号:7
英文摘要	Green manufacturing of catalysts enables sustainable advanced oxidation processes and water treatment processes for removing trace contaminants such as pesticides. An environmentally friendly biosynthesis process produced high-surface-area CuO and NiO nanocatalysts using phytochemicals in the Capparis decidua leaf extract, which served as a reductant and influenced catalyst shape. Capparis decidua is a bushy shrub, widely distributed in dry and arid regions of Africa, Pakistan, India, Egypt, Jordan, Sudan, Saudi Arabia. The synthesized CuO and NiO nanoparticles were characterized by UV-vis spectroscopy (UV-vis), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) and thermo-gravimetric analysis/differential thermal analysis (TGA/DTA). The produced nanoparticles were spherical and flower-like in shape and have a characteristic face-centered cubic structure of CuO and NiO. Biosynthesized catalysts were photoactive and degraded recalcitrant pesticide Lambda-cyhalothrin (L-CHT). Photocatalytic degradation of L-CHT was affected by the initial L-CHT concentration, solution pH levels between 5 and 9, and photocatalyst concentration. The L-CHT removal percentage attained by CuO photocatalyst (similar to 99%) was higher than for NiO photocatalyst (similar to 89%). The degradation of L-CHT follows a pseudo-first-order kinetic model, and the apparent rate constant (k(app)) decreased from 0.033 min(-1) for CuO to 0.0084 min(-1) for NiO photocatalyst. The novel flower-shaped nanoparticles demonstrated high stability in water and recyclability for removing L-CHT pesticide contamination in water.
英文关键词	green synthesis advanced oxidation processes photocatalysis Capparis decidua semiconductor catalysts persistent organic pollutants water treatment
类型	Article
语种	英语
开放获取类型	gold
收录类别	SCI-E
WOS记录号	WOS:000676664200001
WOS关键词	LAMBDA-CYHALOTHRIN ; VISIBLE-LIGHT ; NIO NANOPARTICLES ; OXIDATIVE STRESS ; TIO2 ; SOLAR ; NANOCOMPOSITE ; INVOLVEMENT ; EXPOSURE ; REMOVAL
WOS类目	Chemistry, Physical
WOS研究方向	Chemistry
来源机构	Arizona State University
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/362784
作者单位	[Iqbal, Amna; ul Haq, Atta; Naqvi, Syed Ali Raza] Govt Coll Univ Faisalabad, Dept Chem, Punjab 38000, Pakistan; [Iqbal, Amna; Cerron-Calle, Gabriel Antonio; Westerhoff, Paul; Garcia-Segura, Sergi] Arizona State Univ, Nanosyst Engn Res Ctr Nanotechnol Enabled Water T, Sch Sustainable Engn & Built Environm, Tempe, AZ 85287 USA
推荐引用方式 GB/T 7714	Iqbal, Amna,ul Haq, Atta,Cerron-Calle, Gabriel Antonio,et al. Green Synthesis of Flower-Shaped Copper Oxide and Nickel Oxide Nanoparticles via Capparis decidua Leaf Extract for Synergic Adsorption-Photocatalytic Degradation of Pesticides[J]. Arizona State University,2021,11(7).
APA	Iqbal, Amna,ul Haq, Atta,Cerron-Calle, Gabriel Antonio,Naqvi, Syed Ali Raza,Westerhoff, Paul,&Garcia-Segura, Sergi.(2021).Green Synthesis of Flower-Shaped Copper Oxide and Nickel Oxide Nanoparticles via Capparis decidua Leaf Extract for Synergic Adsorption-Photocatalytic Degradation of Pesticides.CATALYSTS,11(7).
MLA	Iqbal, Amna,et al."Green Synthesis of Flower-Shaped Copper Oxide and Nickel Oxide Nanoparticles via Capparis decidua Leaf Extract for Synergic Adsorption-Photocatalytic Degradation of Pesticides".CATALYSTS 11.7(2021).