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DOI10.1021/acs.energyfuels.1c00317
Multifactor Effects on the Thermal Performances of Molten-Salt Solid-State Lithium-Ion Batteries: A Numerical Study
Lu, Hongfei; Jin, Yang; Zheng, Zhikun
通讯作者Jin, Y (corresponding author), Zhengzhou Univ, Res Ctr Grid Energy Storage & Battery Applicat, Sch Elect Engn, Zhengzhou 450001, Henan, Peoples R China.
来源期刊ENERGY & FUELS
ISSN0887-0624
EISSN1520-5029
出版年2021
卷号35期号:6页码:5360-5371
英文摘要The molten-salt battery is a very suitable battery for large-scale energy storage due to its low cost and excellent L performance. A solid electrolyte-based liquid lithium battery (called SELL battery) is a new type of molten-salt battery with enormous potential for stationary energy storage and extreme environment energy storage such as aerospace and deserts. It has a series of advantages, including the good thermal and chemical performance of the LLZTO electrolyte, lithium anode's high theoretical specific capacity (3860 mA h g(-1)), and recharged high-capacity cathode material. For more stable operation and higher energy utilization efficiency of molten-salt batteries, we designed a thermal-electrochemical coupled 3D SELL battery module model. We successfully realized the module-level long-term (dozens of hours) transient simulation under different operating conditions. Results demonstrate the existence of an optimal charge-discharge rate, which minimizes the sum of the heat generated by the battery and heating plate (31% energy saving compared to battery standing). The heating plate's variable power working mode is more flexible and effective than the constant power working mode. With the increasing thickness of the heat insulation board, energy consumption gradually reduces (energy consumption of which the thickness of heat insulation board equals 3 cm is 3.7 times that of a 12 cm one) and tends to be gentle. A dense array of batteries helps maintain battery temperature and different heating plate shapes have little effect on the average heating plate power. This paper successfully simulated the electrochemical and heat transfer processes of the SELL battery for the first time. It provided a general and efficient numerical simulation method for the molten-salt battery. The results obtained are conducive to improving the molten-salt battery's stability and reducing the battery module's energy consumption.
类型Article
语种英语
收录类别SCI-E
WOS记录号WOS:000631407400062
WOS类目Energy & Fuels ; Engineering, Chemical
WOS研究方向Energy & Fuels ; Engineering
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/350080
作者单位[Lu, Hongfei; Jin, Yang] Zhengzhou Univ, Res Ctr Grid Energy Storage & Battery Applicat, Sch Elect Engn, Zhengzhou 450001, Henan, Peoples R China; [Zheng, Zhikun] State Grid Henan DC Operat & Maintenance Co, Zhengzhou 450000, Henan, Peoples R China
推荐引用方式
GB/T 7714
Lu, Hongfei,Jin, Yang,Zheng, Zhikun. Multifactor Effects on the Thermal Performances of Molten-Salt Solid-State Lithium-Ion Batteries: A Numerical Study[J],2021,35(6):5360-5371.
APA Lu, Hongfei,Jin, Yang,&Zheng, Zhikun.(2021).Multifactor Effects on the Thermal Performances of Molten-Salt Solid-State Lithium-Ion Batteries: A Numerical Study.ENERGY & FUELS,35(6),5360-5371.
MLA Lu, Hongfei,et al."Multifactor Effects on the Thermal Performances of Molten-Salt Solid-State Lithium-Ion Batteries: A Numerical Study".ENERGY & FUELS 35.6(2021):5360-5371.
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