干旱区生态环境知识资源中心(Arid): MIL-160(Al) MOF's potential in adsorptive water harvesting

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DOI	10.1007/s10450-020-00286-5
	MIL-160(Al) MOF's potential in adsorptive water harvesting
	Silva, M. P.; Ribeiro, A. M.; Silva, C. G.; Nogueira, I. B. R.; Cho, Kyung-Ho; Lee, U-Hwang; Faria, J. L.; Loureiro, J. L.; Chang, Jon-San; Rodrigues, A. E.; Ferreira, A.
通讯作者	Ferreira, A (corresponding author), Univ Porto, Associate Lab LSRE LCM, Lab Separat & React Engn, Lab Catalysis & Mat LSRE LCM,Fac Engn, Rua Dr Roberto Frias, P-4200465 Porto, Portugal. ; Chang, JS (corresponding author), Korea Res Inst Chem Technol KRICT, Catalysis Ctr Nanocatalysts, Jang Dong 100, Yuseong, Daejeon, South Korea. ; Chang, JS (corresponding author), Sungkyunkwan Univ, Dept Chem, Suwon 440476, South Korea.
来源期刊	ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
ISSN	0929-5607
EISSN	1572-8757
出版年	2021
卷号	27 期号:2 页码:213-226
英文摘要	The water crisis is one of the main global risks based on its societal impact, particularly the access to safe drinking water in regions with a dry (arid) or mainly dry (semi-arid) climate. Several techniques are being developed, namely the use of regenerative desiccant (e.g., MOFs) to water capture through adsorption processes. MIL-160(Al) belongs to the fumarate-based MOFs family, and it is one of the most promising MOFs for water harvesting and heat transformation applications. In this study, the potential of MIL-160(Al) as an adsorbent for water sorption based applications was evaluated. For this purpose, adsorption equilibrium isotherms, dynamic adsorption experiments, and MIL-160(Al) granules characterization were performed. H2O vapor adsorption equilibrium isotherm was studied at 303, 323, and 343 K presenting a type V shape and was fitted using the Cooperative Multimolecular Sorption model and Polanyi's theory model. Additionally, CO2, N-2, and O-2 adsorption equilibrium isotherms were also measured but at 283, 303, and 323 K, presenting the following order of adsorption affinity: CO2 > O-2 > N-2. Water vapor adsorption breakthrough experiments corroborate the shape of the water adsorption equilibrium isotherms on MIL-160(Al). Water co-adsorption history proved that the presence of the other air components (CO2, O-2, and N-2) does not affect water adsorption behavior on MIL-160(Al). DRIFTS measurements proved the MIL-160(Al) structure remains stable during the water vapor exposure. The optimization of the TSA process allowed us to achieve maximum H2O productivity of 305 L center dot day(-1)center dot ton(-1) for a regeneration temperature of 353 K and flow rate equal to 0.50 m(3)center dot s(-1).
英文关键词	MIL-160(Al) Water Air TSA Optimization
类型	Article
语种	英语
收录类别	SCI-E
WOS记录号	WOS:000604787700002
WOS关键词	METAL-ORGANIC FRAMEWORKS ; HEAT TRANSFORMATION ; SEPARATION ; N-2 ; ADSORBENTS ; NITROGEN ; CAPTURE ; AIR
WOS类目	Chemistry, Physical ; Engineering, Chemical
WOS研究方向	Chemistry ; Engineering
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/347609
作者单位	[Silva, M. P.; Ribeiro, A. M.; Silva, C. G.; Nogueira, I. B. R.; Faria, J. L.; Loureiro, J. L.; Rodrigues, A. E.; Ferreira, A.] Univ Porto, Associate Lab LSRE LCM, Lab Separat & React Engn, Lab Catalysis & Mat LSRE LCM,Fac Engn, Rua Dr Roberto Frias, P-4200465 Porto, Portugal; [Cho, Kyung-Ho; Lee, U-Hwang; Chang, Jon-San] Korea Res Inst Chem Technol KRICT, Catalysis Ctr Nanocatalysts, Jang Dong 100, Yuseong, Daejeon, South Korea; [Chang, Jon-San] Sungkyunkwan Univ, Dept Chem, Suwon 440476, South Korea
推荐引用方式 GB/T 7714	Silva, M. P.,Ribeiro, A. M.,Silva, C. G.,et al. MIL-160(Al) MOF's potential in adsorptive water harvesting[J],2021,27(2):213-226.
APA	Silva, M. P..,Ribeiro, A. M..,Silva, C. G..,Nogueira, I. B. R..,Cho, Kyung-Ho.,...&Ferreira, A..(2021).MIL-160(Al) MOF's potential in adsorptive water harvesting.ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY,27(2),213-226.
MLA	Silva, M. P.,et al."MIL-160(Al) MOF's potential in adsorptive water harvesting".ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY 27.2(2021):213-226.