干旱区生态环境知识资源中心(Arid): Simultaneous determination of seven high risk pesticide residues in royal jelly by high performance liquid chromatography. tandem mass spectrometry

Arid

DOI	10.3724/SP.J.1123.2017.10012
	Simultaneous determination of seven high risk pesticide residues in royal jelly by high performance liquid chromatography. tandem mass spectrometry
	Li Yinghong; Zhou Ping; Xu Quanhua; Zhao Huan; Shao Qiaoyun
通讯作者	Li, YH
来源期刊	CHINESE JOURNAL OF CHROMATOGRAPHY
ISSN	1000-8713
出版年	2018
卷号	36 期号:2 页码:136-142
英文摘要	A method was developed for the simultaneous determination of seven high risk pesticides in the royal jelly, eg. tau-fluvalinate, triadimenol, coumaphos, haloxyfop, carbendazim, thiophanate-ethyl and thiophanate-methyl by high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). First, the royal jelly samples were extracted with acetonitrile under alkaline conditions. After dehydration by anhydrous sodium sulfate, the extracts were enriched and purified through solid-phase extraction (SPE) with Oasis HLB cartridges. Finally, the pesticides were detected by HPLC-MS/MS method. The separation was carried out on a Venusil MP C18 column with gradient elution. Methanol (containing 0.1% (v/v) formic acid) and 0.5 mmol/L ammonium acetate aqueous solution (containing 0.1% (v/v) formic acid) were used as the mobile phases. The detection was achieved using electrospray ionization in positive ion (ESI+) mode and multiple reaction monitoring (MRM) mode for data collection. Quantification was carried out using internal standard method. The results showed that the seven high risk pesticides were linear in the range of 5-100 mu g/kg. The linear correlation coefficients (r(2)) were 0.992 1-0.999 6. The limits of detection (LODs) and limits of quantification (LOQs) of the seven high risk pesticides were 0.5-2.0 mu g/kg and 1.0-5.0 mu g/kg, respectively. The average recoveries at the three spiked levels were 80.5%-101.3%, and the relative stand. ard deviations were 3.6%-9.4% (n = 3). This method is simple, effective and sensitive, and is suitable for the determination of the pesticide residues in royal jelly.
英文关键词	high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) solid-phase extraction (SPE) pesticide residues royal jelly
类型	Article
语种	中文
收录类别	ESCI
WOS记录号	WOS:000429643100007
WOS关键词	EXTRACTION ; FRUIT ; FOODS
WOS类目	Chemistry, Analytical
WOS研究方向	Chemistry
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/332751
作者单位	[Li Yinghong] Zhejiang Inst Food & Drug Control, Hangzhou 310052, Zhejiang, Peoples R China; [Zhou Ping; Xu Quanhua; Zhao Huan; Shao Qiaoyun] Hangzhou Beewords Bee Ind Grp Co Ltd, Tonglu 311500, Peoples R China
推荐引用方式 GB/T 7714	Li Yinghong,Zhou Ping,Xu Quanhua,et al. Simultaneous determination of seven high risk pesticide residues in royal jelly by high performance liquid chromatography. tandem mass spectrometry[J],2018,36(2):136-142.
APA	Li Yinghong,Zhou Ping,Xu Quanhua,Zhao Huan,&Shao Qiaoyun.(2018).Simultaneous determination of seven high risk pesticide residues in royal jelly by high performance liquid chromatography. tandem mass spectrometry.CHINESE JOURNAL OF CHROMATOGRAPHY,36(2),136-142.
MLA	Li Yinghong,et al."Simultaneous determination of seven high risk pesticide residues in royal jelly by high performance liquid chromatography. tandem mass spectrometry".CHINESE JOURNAL OF CHROMATOGRAPHY 36.2(2018):136-142.