干旱区生态环境知识资源中心(Arid): Application of a handheld Raman spectrometer for the screening of colored secondary sulfates in abandoned mining areas-The case of the Sao Domingos Mine (Iberian Pyrite Belt)

Arid

DOI	10.1002/jrs.5873
	Application of a handheld Raman spectrometer for the screening of colored secondary sulfates in abandoned mining areas-The case of the Sao Domingos Mine (Iberian Pyrite Belt)
	Kosek, Filip; Culka, Adam; Fornasini, Laura; Vandenabeele, Peter; Rousaki, Anastasia; Mirao, Jose; Bersani, Danilo; Candeias, Antonio; Jehlicka, Jan
通讯作者	Kosek, F
来源期刊	JOURNAL OF RAMAN SPECTROSCOPY
ISSN	0377-0486
EISSN	1097-4555
出版年	2020
卷号	51 期号:7 页码:1186-1199
英文摘要	The Sao Domingos area (Corte do Pinto, Portugal) represents a large sulfide ore deposit in the Iberian Pyrite Belt that was mined primarily for copper and sulfur in the past. Currently, the deserted mine and mine wastes are the reason for the production of acid mining drainage releasing potentially harmful elements. Because metastable secondary sulfates may temporary sink toxic pollutants, the in situ monitoring of their distribution is required. In this work, we tested a handheld Raman spectrometer equipped with a 532 nm laser excitation for this task. Twelve selected samples of complex composition were analyzed directly in the field using the handheld Raman spectrometer. For comparison, the collected samples were additionally analyzed through laboratory-based Raman spectroscopy and X-ray diffraction. Based on the in situ measurements, rozenite, melanterite, coquimbite, jarosite, metavoltine, chalcanthite, bonattite, antlerite, halotrichite-group minerals, gypsum, and sulfur were detected. The results show that handheld Raman spectrometer is comparable with other laboratory techniques and such handheld systems can be deployed successfully for monitoring of sulfate distribution directly on site.
英文关键词	acid mine drainage handheld Raman instrument sulfates sulfide weathering
类型	Article
语种	英语
收录类别	SCI-E
WOS记录号	WOS:000547711000016
WOS关键词	MICRO-RAMAN ; S. DOMINGOS ; SW SPAIN ; SPECTROSCOPY ; DRAINAGE ; MINERALOGY ; IDENTIFICATION ; HALOTRICHITE ; COQUIMBITE ; APJOHNITE
WOS类目	Spectroscopy
WOS研究方向	Spectroscopy
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/325012
作者单位	[Kosek, Filip; Culka, Adam; Jehlicka, Jan] Charles Univ Prague, Inst Geochem Mineral & Mineral Resources, Fac Sci, Albertov 6, Prague 12843, Czech Republic; [Fornasini, Laura; Bersani, Danilo] Univ Parma, Dept Math Phys & Comp Sci, Parma, Italy; [Vandenabeele, Peter; Rousaki, Anastasia] Univ Ghent, Dept Chem, Ghent, Belgium; [Vandenabeele, Peter] Univ Ghent, Dept Archeol, Ghent, Belgium; [Mirao, Jose; Candeias, Antonio] Univ Evora, HERCULES Lab, Evora, Portugal
推荐引用方式 GB/T 7714	Kosek, Filip,Culka, Adam,Fornasini, Laura,et al. Application of a handheld Raman spectrometer for the screening of colored secondary sulfates in abandoned mining areas-The case of the Sao Domingos Mine (Iberian Pyrite Belt)[J],2020,51(7):1186-1199.
APA	Kosek, Filip.,Culka, Adam.,Fornasini, Laura.,Vandenabeele, Peter.,Rousaki, Anastasia.,...&Jehlicka, Jan.(2020).Application of a handheld Raman spectrometer for the screening of colored secondary sulfates in abandoned mining areas-The case of the Sao Domingos Mine (Iberian Pyrite Belt).JOURNAL OF RAMAN SPECTROSCOPY,51(7),1186-1199.
MLA	Kosek, Filip,et al."Application of a handheld Raman spectrometer for the screening of colored secondary sulfates in abandoned mining areas-The case of the Sao Domingos Mine (Iberian Pyrite Belt)".JOURNAL OF RAMAN SPECTROSCOPY 51.7(2020):1186-1199.