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DOI10.1016/j.lithos.2019.105329
Extreme fractionation and magmatic-hydrothermal transition in the formation of the Abu Dabbab rare-metal granite, Eastern Desert, Egypt
Zoheir, Basem1,2; Lehmann, Bernd3; Emam, Ashraf4; Radwan, Abdelhady4; Zhang, Rongqing5; Bain, Wyatt M.6; Steele-MacInnis, Matthew6; Nolte, Nicole7
通讯作者Zoheir, Basem
来源期刊LITHOS
ISSN0024-4937
EISSN1872-6143
出版年2020
卷号352
英文摘要The Abu Dabbab rare-metal granite in the Central Eastern Desert of Egypt is a peraluminous alkali-feldspar leucogranite stock with minimummelt composition of albite-rich haplogranite and is characterized by economic resources of columbite group minerals (CGM) and cassiterite. The bulk-rock trace element composition is characterized by very low Sr, Ba, REE+Y, Zr, Ti, Ni, Cr concentrations, elevated Li and F, and very high Sn, Ta and Ga. The non-chondritic, low Y/Ho ratios and extremely low Nb/Ta and Zr/Hf ratios of the Abu Dabbab granite are consistent with highly evolved peraluminous granites. The chondrite-normalized REE patterns with significant tetrad effects (TE1,3 similar to 1.6-2.6) and strongly negative Eu anomalies are indicative of the magmatic to hydrothermal transition. Heterogeneous Sm-147/Nd-144 (0.20411-0.51923) and Nd-143/Nd-144 (0.512968-0.514056) values of the bulk-rock reflect a disturbed Sm-Nd isotope system. Nevertheless, the initial epsilon Nd values calculated for a wide range of Neoproterozoic ages (500-700 Ma) are consistently positive, suggesting a juvenile source. Laser ablation ICP-MS analyses of the CGM, cassiterite, wolframite and Mn-ilmenite show elevated rare metal concentrations and complex REE tetrad patterns, reflecting fluid-melt interactions. The metasomatic fluids associated with the Abu Dabbab rare-metal granite were primarily low-salinity (<6 wt.% NaCl eq.), high-density (similar to 0.8-0.9 g/cm(3)), CO2-rich aqueous fluids with up to similar to 50 mol% CO2(+CH4). The minimum entrapment conditions of carbonic-aqueous inclusions are calculated as 2-3 kbar and 350-360 degrees C, whereas aqueous inclusions in the granite and crosscutting quartz veins most likely correspond to lower-pressure conditions and fluid phase separation by decompression. The extreme level of fractionation and complex tetrad effects of the bulk-rock and ore minerals coupled with criteria indicating the magmatic-hydrothermal transition are in accord with regional seismic tomography and heat flow data. A much larger, unexposed parental granite system, from which the exposed Abu Dabbab rare-metal tip has fractionated, must be present at depth. The interaction between extreme fractionation and fluid-melt interaction at shallow crustal levels gave rise to economic-grade Ta-Nb-Sn +/- W mineralization in the granite body and associated quartz veins. (C) 2019 Elsevier B.V. All rights reserved.
英文关键词Abu Dabbab rare-metal granite Egypt Elemental and isotopic data Extreme fractionation Magmatic-hydrothermal transition
类型Article
语种英语
国家Egypt ; Germany ; Peoples R China ; Canada
收录类别SCI-E
WOS记录号WOS:000515201500031
WOS关键词A-TYPE GRANITES ; COLUMBITE-TANTALITE MINERALS ; LA-ICP-MS ; FLUID INCLUSIONS ; TRACE-ELEMENTS ; BEARING LEUKOGRANITE ; CHEMICAL EVOLUTION ; TA MINERALIZATION ; GEOCHEMISTRY ; TIN
WOS类目Geochemistry & Geophysics ; Mineralogy
WOS研究方向Geochemistry & Geophysics ; Mineralogy
来源机构南京大学
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/315146
作者单位1.Benha Univ, Fac Sci, Dept Geol, Banha 13518, Egypt;
2.Univ Kiel, Inst Geosci, Ludewig Meyn Str 10, D-24118 Kiel, Germany;
3.Tech Univ Clausthal, Mineral Resources, D-38678 Clausthal Zellerfeld, Germany;
4.Aswan Univ, Fac Sci, Dept Geol, Aswan 81528, Egypt;
5.Nanjing Univ, Dept Earth Sci, Nanjing 210093, Peoples R China;
6.Univ Alberta, Dept Earth & Atmospher Sci, Edmonton, AB T6G 2E3, Canada;
7.Geosci Ctr, Dept Isotope Geol, D-337077 Gottingen, Germany
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Zoheir, Basem,Lehmann, Bernd,Emam, Ashraf,et al. Extreme fractionation and magmatic-hydrothermal transition in the formation of the Abu Dabbab rare-metal granite, Eastern Desert, Egypt[J]. 南京大学,2020,352.
APA Zoheir, Basem.,Lehmann, Bernd.,Emam, Ashraf.,Radwan, Abdelhady.,Zhang, Rongqing.,...&Nolte, Nicole.(2020).Extreme fractionation and magmatic-hydrothermal transition in the formation of the Abu Dabbab rare-metal granite, Eastern Desert, Egypt.LITHOS,352.
MLA Zoheir, Basem,et al."Extreme fractionation and magmatic-hydrothermal transition in the formation of the Abu Dabbab rare-metal granite, Eastern Desert, Egypt".LITHOS 352(2020).
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