干旱区生态环境知识资源中心(Arid): Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester

Arid

DOI	10.1021/acscentsci.9b00745
	Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester
	Hanikel, Nikita 1,2,3,4; Prevot, Mathieu S.1,2,3,4; Fathieh, Farhad 1,2,3,4; Kapustin, Eugene A.1,2,3,4; Lyu, Hao 1,2,3,4; Wang, Haoze 1,2,3,4; Diercks, Nicolas J.1,2,3,4; Glover, T. Grant 5; Yaghi, Omar M.1,2,3,4,6
通讯作者	Yaghi, Omar M.
来源期刊	ACS CENTRAL SCIENCE
ISSN	2374-7943
EISSN	2374-7951
出版年	2019
卷号	5 期号:10 页码:1699-1706
英文摘要	Sorbent-assisted water harvesting from air represents an attractive way to address water scarcity in arid climates. Hitherto, sorbents developed for this technology have exclusively been designed to perform one water harvesting cycle (WHC) per day, but the productivities attained with this approach cannot reasonably meet the rising demand for drinking water. This work shows that a microporous aluminum-based metal-organic framework, MOF-303, can perform an adsorption- desorption cycle within minutes under a mild temperature swing, which opens the way for high-productivity water harvesting through rapid, continuous WHCs. Additionally, the favorable dynamic water sorption properties of MOF-303 allow it to outperform other commercial sorbents displaying excellent steady-state characteristics under similar experimental conditions. Finally, these findings are implemented in a new water harvester capable of generating 1.3 L kg(MOF)(-1 )day(-1) in an indoor arid environment (32% relative humidity, 27 degrees C) and 0.7 L kg(MOF)(-1 )day(-1) in the Mojave Desert (in conditions as extreme as 10% RH, 27 degrees C), representing an improvement by 1 order of magnitude over previously reported devices. This study demonstrates that creating sorbents capable of rapid water sorption dynamics, rather than merely focusing on high water capacities, is crucial to reach water production on a scale matching human consumption.
类型	Article
语种	英语
国家	USA ; Saudi Arabia
开放获取类型	gold, Green Published
收录类别	SCI-E
WOS记录号	WOS:000492698300013
WOS关键词	ADSORPTION ; PROFILES ; MIL-101
WOS类目	Chemistry, Multidisciplinary
WOS研究方向	Chemistry
EI主题词	2019-10-23
来源机构	University of California, Berkeley
资源类型	期刊论文
条目标识符	http://119.78.100.177/qdio/handle/2XILL650/310338
作者单位	1.Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA; 2.Lawrence Berkeley Natl Lab, Mat Sci Div, Berkeley, CA 94720 USA; 3.Kavli Energy NanoSci Inst, Berkeley, CA 94720 USA; 4.Berkeley Global Sci Inst, Berkeley, CA 94720 USA; 5.Univ S Alabama, Dept Chem & Biomol Engn, Mobile, AL 36688 USA; 6.UC Berkeley, KACST Joint Ctr Excellence Nanomat Clean Energy A, King Abdulaziz City Sci & Technol, Riyadh 11442, Saudi Arabia
推荐引用方式 GB/T 7714	Hanikel, Nikita,Prevot, Mathieu S.,Fathieh, Farhad,et al. Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester[J]. University of California, Berkeley,2019,5(10):1699-1706.
APA	Hanikel, Nikita.,Prevot, Mathieu S..,Fathieh, Farhad.,Kapustin, Eugene A..,Lyu, Hao.,...&Yaghi, Omar M..(2019).Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester.ACS CENTRAL SCIENCE,5(10),1699-1706.
MLA	Hanikel, Nikita,et al."Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester".ACS CENTRAL SCIENCE 5.10(2019):1699-1706.