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This paper addressed the retrieval of land surface temperature (LST) from combined mid-infrared and thermal infrared data of the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-Orbiting Partnership (S-NPP). To efficiently remove the effect of the direct solar radiance, a relationship between direct solar radiance and water vapor content, view zenith angle and solar zenith angle is proposed to improve the retrieve accuracy. Then, a split-window algorithm from combined mid-infrared and thermal infrared data is used to correct for the atmospheric effects and retrieve the LST with the aid of emissivity provide by VIIRS product. Finally, comparison of the standard VIIRS LST product and the retrieved LST from the proposed algorithm, a good agreement was shown. Analysis indicated the root mean square error (RMSE) of the LST over these land cover types is 2.04K for desert and 1.84K for vegetation, respectively.