Arid
DOI10.1016/j.jes.2015.08.018
Heterogeneous uptake of gaseous hydrogen peroxide on mineral dust
Zhou, Li; Wang, Weigang; Ge, Maofa; Tong, Shengrui
通讯作者Wang, Weigang ; Ge, Maofa
会议名称4th Sino-French Workshop
会议日期DEC 10-13, 2014
会议地点Lyon, FRANCE
英文摘要

The heterogeneous uptake processes of hydrogen peroxide on Arizona test dust and two types of authentic Chinese mineral dusts, i.e., Inner Mongolia desert dust and Xinjiang calciferous dust, were investigated using a Knudsen cell reactor coupled with a quadrupole mass spectrometer. The uptake coefficients were measured as a function of the initial concentration of H2O2 from 2.6 x 10(11) to 1.2 x 10(12) molecules/cm(3), and the temperature dependence of the uptake coefficients was investigated over a range from 253 to 313 K. The concentration of H2O2 showed little effect on the uptake coefficients of these heterogeneous processes. As a function of temperature, the initial uptake coefficients decrease with increasing temperature, whereas the steady state uptake coefficients of Arizona test dust and Inner Mongolia desert dust increase with increasing temperature. Implications for the understanding of the uptake processes onto mineral dust samples were also discussed. (C) 2015 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.


英文关键词Hydrogen peroxide Mineral dust Heterogeneous uptake Uptake coefficients
来源出版物JOURNAL OF ENVIRONMENTAL SCIENCES
ISSN1001-0742
EISSN1878-7320
出版年2016
卷号40
页码44-50
出版者SCIENCE PRESS
类型Article;Proceedings Paper
语种英语
国家Peoples R China
收录类别SCI-E ; CPCI-S
WOS记录号WOS:000372093200007
WOS关键词SOLID PARTICLE SURFACES ; KNUDSEN CELL REACTOR ; ORGANIC HYDROPEROXIDES ; TEMPERATURE-DEPENDENCE ; ATMOSPHERIC REACTIONS ; RELATIVE-HUMIDITY ; CALCIUM-CARBONATE ; TIO2 SURFACE ; ICE SURFACES ; NITRIC-ACID
WOS类目Environmental Sciences
WOS研究方向Environmental Sciences & Ecology
资源类型会议论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/305299
作者单位Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Li,Wang, Weigang,Ge, Maofa,et al. Heterogeneous uptake of gaseous hydrogen peroxide on mineral dust[C]:SCIENCE PRESS,2016:44-50.
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