Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1016/j.jes.2015.08.018 |
Heterogeneous uptake of gaseous hydrogen peroxide on mineral dust | |
Zhou, Li; Wang, Weigang; Ge, Maofa; Tong, Shengrui | |
通讯作者 | Wang, Weigang ; Ge, Maofa |
会议名称 | 4th Sino-French Workshop |
会议日期 | DEC 10-13, 2014 |
会议地点 | Lyon, FRANCE |
英文摘要 | The heterogeneous uptake processes of hydrogen peroxide on Arizona test dust and two types of authentic Chinese mineral dusts, i.e., Inner Mongolia desert dust and Xinjiang calciferous dust, were investigated using a Knudsen cell reactor coupled with a quadrupole mass spectrometer. The uptake coefficients were measured as a function of the initial concentration of H2O2 from 2.6 x 10(11) to 1.2 x 10(12) molecules/cm(3), and the temperature dependence of the uptake coefficients was investigated over a range from 253 to 313 K. The concentration of H2O2 showed little effect on the uptake coefficients of these heterogeneous processes. As a function of temperature, the initial uptake coefficients decrease with increasing temperature, whereas the steady state uptake coefficients of Arizona test dust and Inner Mongolia desert dust increase with increasing temperature. Implications for the understanding of the uptake processes onto mineral dust samples were also discussed. (C) 2015 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. |
英文关键词 | Hydrogen peroxide Mineral dust Heterogeneous uptake Uptake coefficients |
来源出版物 | JOURNAL OF ENVIRONMENTAL SCIENCES |
ISSN | 1001-0742 |
EISSN | 1878-7320 |
出版年 | 2016 |
卷号 | 40 |
页码 | 44-50 |
出版者 | SCIENCE PRESS |
类型 | Article;Proceedings Paper |
语种 | 英语 |
国家 | Peoples R China |
收录类别 | SCI-E ; CPCI-S |
WOS记录号 | WOS:000372093200007 |
WOS关键词 | SOLID PARTICLE SURFACES ; KNUDSEN CELL REACTOR ; ORGANIC HYDROPEROXIDES ; TEMPERATURE-DEPENDENCE ; ATMOSPHERIC REACTIONS ; RELATIVE-HUMIDITY ; CALCIUM-CARBONATE ; TIO2 SURFACE ; ICE SURFACES ; NITRIC-ACID |
WOS类目 | Environmental Sciences |
WOS研究方向 | Environmental Sciences & Ecology |
资源类型 | 会议论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/305124 |
作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Li,Wang, Weigang,Ge, Maofa,et al. Heterogeneous uptake of gaseous hydrogen peroxide on mineral dust[C]:SCIENCE PRESS,2016:44-50. |
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