Arid
DOI10.1063/1.4803409
Atmospheric Ice Nucleation by Fertile Soil Dusts Particles: Relative Importance of Mineral and Biological Components
O'; Sullivan, Daniel1; Murray, B. J.1; Malkin, T. L.1; Webb, M. E.2; Whale, T. F.1; Atkinson, J. D.1; Baustian, K. J.1
通讯作者O&#39 ; Sullivan, Daniel
会议名称19th International Conference on Nucleation and Atmospheric Aerosols (ICNAA)
会议日期JUN 23-28, 2013
会议地点Fort Collins, CO
英文摘要

Dusts emitted from agricultural soils may represent a significant source of atmospheric particulates at mid-latitudes. Such dusts, which can be aerosolised by anthropogenic agricultural activities, have previously been estimated to be present in the atmosphere at sufficient number densities that they could potentially compete with other known ice nuclei (IN). In contrast to soils from arid regions, such as the Sahara, fertile soils contain a larger fraction of biological material, which can lead to an enhancement in the ice nucleating ability of their associated dusts. However, considerable uncertainties remain regarding the relative efficacy of soil dust particles from fertile soils as IN. Using an experimental methodology designed to increase sensitivity to a wide range of ice nucleation efficiencies, we have characterized the immersion mode ice nucleating activities of sub 11 mu m particles extracted from surface soils collected in four locations around England. By using a variety of droplet sizes, from pico-to micro-litre, we have been able to characterize the ice active site densities in soils (estimated using a time-independent framework) at temperatures ranging from -5 degrees C down to the homogeneous limit of freezing at similar to -36 degrees C. At temperatures below -15 degrees C, we find that the ice active site densities tend towards those expected from the mineral components in the soils, suggesting that the inorganic fraction of soil dusts becomes increasingly important in the initiation of the ice phase at large supercoolings. Conversely, above -15 degrees C we find that the ice nucleating activity of the soils dusts was larger than expected from the mineral composition of the soils. The sites responsible for this high temperature ice nucleating activity were sensitive to heat treatment and digestion with hydrogen peroxide, suggesting that they are biological in origin. We conclude that although only being a relatively minor contributor to the global atmospheric dust burden, the enhanced IN activities of dusts generated from agricultural activities may impact upon cloud glaciation, particularly at temperatures above -15 degrees C.


英文关键词Soil Dust Immersion Mode Ice Nucleation Mixed Phase Clouds Cloud Glaciation
来源出版物NUCLEATION AND ATMOSPHERIC AEROSOLS
ISSN0094-243X
出版年2013
卷号1527
页码871-874
EISBN978-0-7354-1152-4
出版者AMER INST PHYSICS
类型Proceedings Paper
语种英语
国家England
收录类别CPCI-S
WOS记录号WOS:000319766400217
WOS类目Physics, Applied
WOS研究方向Physics
资源类型会议论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/301392
作者单位1.Univ Leeds, Sch Earth & Environm, Leeds LS2 9JT, W Yorkshire, England;
2.Univ Leeds, Sch Chem, Leeds, W Yorkshire, England
推荐引用方式
GB/T 7714
O',Sullivan, Daniel,Murray, B. J.,et al. Atmospheric Ice Nucleation by Fertile Soil Dusts Particles: Relative Importance of Mineral and Biological Components[C]:AMER INST PHYSICS,2013:871-874.
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