Arid
DOI10.1016/j.sab.2006.01.013
Single-particle characterization of "Asian Dust" certified reference materials using low-Z particle electron probe X-ray microanalysis
Hwang, HeeJin; Ro, Chul-Un
通讯作者Ro, Chul-Un
会议名称34th Colloquium Spectroscopicum Internationale
会议日期SEP 04-09, 2005
会议地点Antwerp, BELGIUM
英文摘要

In order to clearly elucidate whether Asian Dust particles experience chemical modification during long-range transport, it is necessary to characterize soil particles where Asian Dust particles originate. If chemical compositions of source soil particles are well characterized, then chemical compositions of Asian Dust particles collected outside source regions can be compared with those of source soil particles in order to find out the occurrence of chemical modification. Asian Dust particles are chemically and morphologically heterogeneous, and thus the average composition and the average aerodynamic diameter (obtainable by bulk analysis) are not much relevant if the chemical modifications of the particles must be followed. The major elemental composition and abundance of the particle types that are potential subjects of chemical modification can only be obtained using single-particle analysis. A single particle analytical technique, named low-Zparticle electron probe X-ray microanalysis (low-Zparticle EPMA), was applied to characterize two certified reference materials (CRMs) for Asian Dust particles, which were collected from a loess plateau area and a desert of China. The CRMs were defined by bulk analyses to provide certified concentrations for 13 chemical elements. Using the low-Z particle EPMA technique, the concentrations of major chemical species such as aluminosilicates, SiO2, CaCO3, and carbonaccous species were obtained. Elemental concentrations obtained by the low-Z particle EPMA, are close to the certified values, with considering that the single particle and bulk analyses employ very different approaches. There are still some discrepancies between those concentration values, resulting from analyses of particles with different sizes, different sample amounts analyzed, and uncertainties involved in the single particle analysis. (c) 2006 Elsevier B.V. All rights reserved.


英文关键词CRMs Asian Dust aerosols single particle analysis low-Z particle EPMA electron probe X-ray microanalysis
来源出版物SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
ISSN0584-8547
出版年2006
卷号61
期号4
页码400-406
出版者PERGAMON-ELSEVIER SCIENCE LTD
类型Article;Proceedings Paper
语种英语
国家South Korea
收录类别SCI-E ; CPCI-S
WOS记录号WOS:000238887600005
WOS关键词LONG-RANGE TRANSPORT ; SEA-SALT ; ATMOSPHERIC PARTICLES ; STORM PARTICLES ; MINERAL AEROSOL ; HETEROGENEOUS CHEMISTRY ; INDIVIDUAL PARTICLES ; CHEMICAL SPECIATION ; RELATIVE ROLES ; NORTH PACIFIC
WOS类目Spectroscopy
WOS研究方向Spectroscopy
资源类型会议论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/296283
作者单位(1)Inha Univ, Dept Chem, Inchon 402751, South Korea
推荐引用方式
GB/T 7714
Hwang, HeeJin,Ro, Chul-Un. Single-particle characterization of "Asian Dust" certified reference materials using low-Z particle electron probe X-ray microanalysis[C]:PERGAMON-ELSEVIER SCIENCE LTD,2006:400-406.
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