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DOI | 10.1007/s10973-005-7549-z |
Evaluation of the residual stability of polyurethane automotive coatings by DSC - Equivalence of Xenotest and desert weathering tests and the synergism of stabilizers | |
Simon, P.; Fratricova, Marta; Schwarzer, P.; Wilde, H. -W. | |
通讯作者 | Simon, P. |
会议名称 | 17th TERMANAL Conference |
会议日期 | OCT 02-05, 2005 |
会议地点 | Stara Lesna, SLOVAKIA |
英文摘要 | Degradation of poly(ester-urethanes), poly(ether-urethanes) and poly(acrylic-urethanes), as a base for automotive paintings in interior applications, has been studied by DSC. The samples were clearcoat and black-pigmented paints, unstabilized and stabilized with HALS Tinuvin 292, UV absorber Tinuvin 1130 and antioxidant Hostanox O3, exposed to weathering in Xenotest and in Arizona desert. From the dependences of oxidation onset temperature on the heating rate, the kinetic parameters enabling to calculate the oxidation induction time for a chosen temperature have been obtained. From the values of oxidation induction time, the protection factors of the additives and the residual stability of the polymer after an ageing stress has been evaluated. It has been shown that the equivalence between the two methods of weathering depends on the polymer composition. A new criterion for the evaluation of synergism/antagonism of additives in the stabilizing mixture has been proposed. |
英文关键词 | accelerated ageing automotive coating DSC polyurethane residual stability synergism thermooxidation |
来源出版物 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY |
ISSN | 1388-6150 |
出版年 | 2006 |
卷号 | 84 |
期号 | 3 |
页码 | 679-692 |
出版者 | SPRINGER |
类型 | Article;Proceedings Paper |
语种 | 英语 |
国家 | Slovakia;Germany |
收录类别 | SCI-E ; CPCI-S |
WOS记录号 | WOS:000238157400024 |
WOS关键词 | SEGMENTED POLYURETHANES ; PHOTOCHEMICAL BEHAVIOR ; INDUCTION PERIODS ; INFRARED-ANALYSIS ; CHEMILUMINESCENCE |
WOS类目 | Thermodynamics ; Chemistry, Analytical ; Chemistry, Physical |
WOS研究方向 | Thermodynamics ; Chemistry |
资源类型 | 会议论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/296048 |
作者单位 | (1)Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Dept Phys Chem, Bratislava 81237, Slovakia;(2)Volkswagen AG, D-38436 Wolfsburg, Germany;(3)Mankiewicz Gebr & Co, D-21107 Hamburg, Germany |
推荐引用方式 GB/T 7714 | Simon, P.,Fratricova, Marta,Schwarzer, P.,et al. Evaluation of the residual stability of polyurethane automotive coatings by DSC - Equivalence of Xenotest and desert weathering tests and the synergism of stabilizers[C]:SPRINGER,2006:679-692. |
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