Arid
DOI10.1007/s10973-005-7549-z
Evaluation of the residual stability of polyurethane automotive coatings by DSC - Equivalence of Xenotest and desert weathering tests and the synergism of stabilizers
Simon, P.; Fratricova, Marta; Schwarzer, P.; Wilde, H. -W.
通讯作者Simon, P.
会议名称17th TERMANAL Conference
会议日期OCT 02-05, 2005
会议地点Stara Lesna, SLOVAKIA
英文摘要

Degradation of poly(ester-urethanes), poly(ether-urethanes) and poly(acrylic-urethanes), as a base for automotive paintings in interior applications, has been studied by DSC. The samples were clearcoat and black-pigmented paints, unstabilized and stabilized with HALS Tinuvin 292, UV absorber Tinuvin 1130 and antioxidant Hostanox O3, exposed to weathering in Xenotest and in Arizona desert. From the dependences of oxidation onset temperature on the heating rate, the kinetic parameters enabling to calculate the oxidation induction time for a chosen temperature have been obtained. From the values of oxidation induction time, the protection factors of the additives and the residual stability of the polymer after an ageing stress has been evaluated. It has been shown that the equivalence between the two methods of weathering depends on the polymer composition. A new criterion for the evaluation of synergism/antagonism of additives in the stabilizing mixture has been proposed.


英文关键词accelerated ageing automotive coating DSC polyurethane residual stability synergism thermooxidation
来源出版物JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN1388-6150
出版年2006
卷号84
期号3
页码679-692
出版者SPRINGER
类型Article;Proceedings Paper
语种英语
国家Slovakia;Germany
收录类别SCI-E ; CPCI-S
WOS记录号WOS:000238157400024
WOS关键词SEGMENTED POLYURETHANES ; PHOTOCHEMICAL BEHAVIOR ; INDUCTION PERIODS ; INFRARED-ANALYSIS ; CHEMILUMINESCENCE
WOS类目Thermodynamics ; Chemistry, Analytical ; Chemistry, Physical
WOS研究方向Thermodynamics ; Chemistry
资源类型会议论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/296048
作者单位(1)Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Dept Phys Chem, Bratislava 81237, Slovakia;(2)Volkswagen AG, D-38436 Wolfsburg, Germany;(3)Mankiewicz Gebr & Co, D-21107 Hamburg, Germany
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Simon, P.,Fratricova, Marta,Schwarzer, P.,et al. Evaluation of the residual stability of polyurethane automotive coatings by DSC - Equivalence of Xenotest and desert weathering tests and the synergism of stabilizers[C]:SPRINGER,2006:679-692.
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