Arid
DOI10.1557/PROC-663-979
Geochemistry of hydrothermal veins containing zirconolite and betafite at Adamello, Italy
Giere, R; Lumpkin, GR; Williams, CT; Smith, KL; Payne, TE; Meglinn, PJ; Hart, KP; Oberli, F
通讯作者Giere, R
会议名称24th International Symposium on Scientific Basis for Nuclear Waste Management
会议日期AUG 27-31, 2000
会议地点SYDNEY, AUSTRALIA
英文摘要

Hydrothermal veins containing zirconolite and betafite occur in dolomite marbles at the contact with a tonalite intrusion of the Adamello batholith, Italy. The veins display four distinct mineral zones and are highly enriched in Th, U, Ti, Zr, Nb, and rare earth elements (REE) relative to their host rock. Wide ranges in concentration of these elements and distinct interelement fractionation trends exist across the four vein zones. The behavior of Th closely reflects that of P, Ti, Nb, and heavy REE, but was distinct from that of U, Zr and light REE (La to Sm). The presence and composition of refractory minerals such as zirconolite, betafite, uraninite, thorianite, baddeleyite, rutile, allanite, and aeschynite provide evidence for the transport of Ti, Zr, Nb, REE, and actinides by a fluid, which was further characterized by a low pH and high contents of F, P, Cl and H2S. Thermodynamic analysis of these veins indicates that they were formed at 550-600 degreesC, 200 MPa total pressure, arid from a fluid derived from the tonalite. Mineralogical and textural observations suggest that crystallization of the refractory minerals was in part induced by precipitation of fluorapatite and sulfides. The geochemical data further indicate that precipitation of light REE was induced by the fluid/wall-rock interaction which led to a significant dilution of the fluid by CO2. The studied veins provide an example of high-temperature transport of actinides and REE in the Earth's crust and show that these elements can be precipitated from a fluid and subsequently immobilized by zirconolite and betafite, two important actinide hosts in ceramic nuclear waste forms.


来源出版物SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXIV
ISSN0272-9172
出版年2000
卷号663
页码979-987
ISBN1-55899-598-6
出版者MATERIALS RESEARCH SOCIETY
类型Proceedings Paper
语种英语
国家USA
收录类别CPCI-S
WOS记录号WOS:000179468500110
WOS关键词TEMPERATURES ; PRESSURES ; ELEMENTS ; ANALOGS ; FLUIDS ; REE
WOS类目Materials Science, Multidisciplinary ; Nuclear Science & Technology
WOS研究方向Materials Science ; Nuclear Science & Technology
资源类型会议论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/293210
作者单位(1)Purdue Univ, W Lafayette, IN 47907 USA
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Giere, R,Lumpkin, GR,Williams, CT,et al. Geochemistry of hydrothermal veins containing zirconolite and betafite at Adamello, Italy[C]:MATERIALS RESEARCH SOCIETY,2000:979-987.
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