Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1557/PROC-663-979 |
Geochemistry of hydrothermal veins containing zirconolite and betafite at Adamello, Italy | |
Giere, R; Lumpkin, GR; Williams, CT; Smith, KL; Payne, TE; Meglinn, PJ; Hart, KP; Oberli, F | |
通讯作者 | Giere, R |
会议名称 | 24th International Symposium on Scientific Basis for Nuclear Waste Management |
会议日期 | AUG 27-31, 2000 |
会议地点 | SYDNEY, AUSTRALIA |
英文摘要 | Hydrothermal veins containing zirconolite and betafite occur in dolomite marbles at the contact with a tonalite intrusion of the Adamello batholith, Italy. The veins display four distinct mineral zones and are highly enriched in Th, U, Ti, Zr, Nb, and rare earth elements (REE) relative to their host rock. Wide ranges in concentration of these elements and distinct interelement fractionation trends exist across the four vein zones. The behavior of Th closely reflects that of P, Ti, Nb, and heavy REE, but was distinct from that of U, Zr and light REE (La to Sm). The presence and composition of refractory minerals such as zirconolite, betafite, uraninite, thorianite, baddeleyite, rutile, allanite, and aeschynite provide evidence for the transport of Ti, Zr, Nb, REE, and actinides by a fluid, which was further characterized by a low pH and high contents of F, P, Cl and H2S. Thermodynamic analysis of these veins indicates that they were formed at 550-600 degreesC, 200 MPa total pressure, arid from a fluid derived from the tonalite. Mineralogical and textural observations suggest that crystallization of the refractory minerals was in part induced by precipitation of fluorapatite and sulfides. The geochemical data further indicate that precipitation of light REE was induced by the fluid/wall-rock interaction which led to a significant dilution of the fluid by CO2. The studied veins provide an example of high-temperature transport of actinides and REE in the Earth's crust and show that these elements can be precipitated from a fluid and subsequently immobilized by zirconolite and betafite, two important actinide hosts in ceramic nuclear waste forms. |
来源出版物 | SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXIV |
ISSN | 0272-9172 |
出版年 | 2000 |
卷号 | 663 |
页码 | 979-987 |
ISBN | 1-55899-598-6 |
出版者 | MATERIALS RESEARCH SOCIETY |
类型 | Proceedings Paper |
语种 | 英语 |
国家 | USA |
收录类别 | CPCI-S |
WOS记录号 | WOS:000179468500110 |
WOS关键词 | TEMPERATURES ; PRESSURES ; ELEMENTS ; ANALOGS ; FLUIDS ; REE |
WOS类目 | Materials Science, Multidisciplinary ; Nuclear Science & Technology |
WOS研究方向 | Materials Science ; Nuclear Science & Technology |
资源类型 | 会议论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/293210 |
作者单位 | (1)Purdue Univ, W Lafayette, IN 47907 USA |
推荐引用方式 GB/T 7714 | Giere, R,Lumpkin, GR,Williams, CT,et al. Geochemistry of hydrothermal veins containing zirconolite and betafite at Adamello, Italy[C]:MATERIALS RESEARCH SOCIETY,2000:979-987. |
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