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Temperature and irradiance effect on the photovoltaic parameters of a fullerene/conjugated-polymer solar cell | |
Katz, EA; Faiman, D; Cohen, Y; Padinger, F; Brabec, C; Sariciftci, NS | |
通讯作者 | Katz, EA |
会议名称 | Conference on Organic Photovoltaics |
会议日期 | AUG 03, 2000 |
会议地点 | SAN DIEGO, CA |
英文摘要 | Bulk donor-acceptor heterojunctions between conjugated polymers and fullerene derivatives have been utilized successfully for photovoltaic devices showing monochromatic efficiencies above 1 %. The present paper reports the temperature and irradiance dependencies of full-spectrum photovoltaic parameters for such devices. The measurements were performed under real sun conditions and under a solar simulator. The sun provided a light source stable in intensity to within +/-1% and closely approximating a true AM1.5 spectrum, whereas the simulator enabled the light intensity to be varied in the range 80-600 W m(-2). The most interesting feature that was observed for these devices is that above a cell temperature of 20 degreesC the positive temperature coefficient observed for the short-circuit current exceeds in magnitude the negative temperature coefficient that was found for the open-circuit voltage. This means that, unlike the situation for conventional PV devices, these cells actually exhibit an increase in efficiency with increasing temperature (reaching a value of 0.63 % at 40 degreesC). We suggest that the observed behavior originates from the temperature dependence of the conductivity of the conjugated polymers-fullerene composite. This hypothesis is confirmed by the irradiance-resolved measurements performed at different cell temperatures. We observe a linear increase in the short-circuit current with light intensity over the whole ranges of irradiances and temperatures but maximum temperature influence is observed at highest light intensity. |
英文关键词 | bulk heterojunctions fullerenes conjugated polymers solar cells |
来源出版物 | ORGANIC PHOTOVOLTAICS |
ISSN | 0277-786X |
出版年 | 2000 |
卷号 | 4108 |
页码 | 117-124 |
ISBN | 0-8194-3753-0 |
出版者 | SPIE-INT SOC OPTICAL ENGINEERING |
类型 | Proceedings Paper |
语种 | 英语 |
国家 | Israel |
收录类别 | CPCI-S |
WOS记录号 | WOS:000168536800014 |
WOS关键词 | PHOTOINDUCED ELECTRON-TRANSFER ; DONOR-ACCEPTOR HETEROJUNCTIONS ; COMPOSITES ; DIODES ; BUCKMINSTERFULLERENE ; PHOTODIODES ; DESERT |
WOS类目 | Engineering, Electrical & Electronic ; Optics |
WOS研究方向 | Engineering ; Optics |
资源类型 | 会议论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/293133 |
作者单位 | (1)Ben Gurion Univ Negev, Jacob Blaustein Inst Desert Res, Ben Gurion Natl Solar Energy Ctr, IL-89990 Sede Boqer, Israel |
推荐引用方式 GB/T 7714 | Katz, EA,Faiman, D,Cohen, Y,et al. Temperature and irradiance effect on the photovoltaic parameters of a fullerene/conjugated-polymer solar cell[C]:SPIE-INT SOC OPTICAL ENGINEERING,2000:117-124. |
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