Arid
Temperature and irradiance effect on the photovoltaic parameters of a fullerene/conjugated-polymer solar cell
Katz, EA; Faiman, D; Cohen, Y; Padinger, F; Brabec, C; Sariciftci, NS
通讯作者Katz, EA
会议名称Conference on Organic Photovoltaics
会议日期AUG 03, 2000
会议地点SAN DIEGO, CA
英文摘要

Bulk donor-acceptor heterojunctions between conjugated polymers and fullerene derivatives have been utilized successfully for photovoltaic devices showing monochromatic efficiencies above 1 %. The present paper reports the temperature and irradiance dependencies of full-spectrum photovoltaic parameters for such devices. The measurements were performed under real sun conditions and under a solar simulator. The sun provided a light source stable in intensity to within +/-1% and closely approximating a true AM1.5 spectrum, whereas the simulator enabled the light intensity to be varied in the range 80-600 W m(-2). The most interesting feature that was observed for these devices is that above a cell temperature of 20 degreesC the positive temperature coefficient observed for the short-circuit current exceeds in magnitude the negative temperature coefficient that was found for the open-circuit voltage. This means that, unlike the situation for conventional PV devices, these cells actually exhibit an increase in efficiency with increasing temperature (reaching a value of 0.63 % at 40 degreesC). We suggest that the observed behavior originates from the temperature dependence of the conductivity of the conjugated polymers-fullerene composite. This hypothesis is confirmed by the irradiance-resolved measurements performed at different cell temperatures. We observe a linear increase in the short-circuit current with light intensity over the whole ranges of irradiances and temperatures but maximum temperature influence is observed at highest light intensity.


英文关键词bulk heterojunctions fullerenes conjugated polymers solar cells
来源出版物ORGANIC PHOTOVOLTAICS
ISSN0277-786X
出版年2000
卷号4108
页码117-124
ISBN0-8194-3753-0
出版者SPIE-INT SOC OPTICAL ENGINEERING
类型Proceedings Paper
语种英语
国家Israel
收录类别CPCI-S
WOS记录号WOS:000168536800014
WOS关键词PHOTOINDUCED ELECTRON-TRANSFER ; DONOR-ACCEPTOR HETEROJUNCTIONS ; COMPOSITES ; DIODES ; BUCKMINSTERFULLERENE ; PHOTODIODES ; DESERT
WOS类目Engineering, Electrical & Electronic ; Optics
WOS研究方向Engineering ; Optics
资源类型会议论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/293133
作者单位(1)Ben Gurion Univ Negev, Jacob Blaustein Inst Desert Res, Ben Gurion Natl Solar Energy Ctr, IL-89990 Sede Boqer, Israel
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Katz, EA,Faiman, D,Cohen, Y,et al. Temperature and irradiance effect on the photovoltaic parameters of a fullerene/conjugated-polymer solar cell[C]:SPIE-INT SOC OPTICAL ENGINEERING,2000:117-124.
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