Arid
DOI10.2172/460199
报告编号CONF-961107--Absts.
来源IDOSTI_ID: 460199
Structure{leftrightarrow}property relationships in solid oxide fuel cells
Huebner, W.; Reed, D.M.; Anderson, H.U. [Univ. of Missouri, Rolla, MO (United States)]
英文摘要The electrode reactions are a major cause of the energy losses in SOFC`s, and limit their use to higher temperatures, typically 800-1000{degrees}C. The electrode reactions have received much attention aimed at better understanding the electrode kinetics and mechanisms, but are still very primitive in their basic understanding. The electrode microstructure and its corresponding reactivity has commonly been studied by DC and AC impedance techniques. A common method of examining electrode reactions employs surface-mounted reference electrodes, although this technique often limits the experiment to examination of one electrode. In this study a new technique has been developed of utilizing a Pt voltage probe placed internally into the electrolyte to measure the IN and impedance spectra of both electrodes operating under cell conditions. Unlike surface mounted electrodes which need to be concerned with distance and dimensions of reference electrodes with respect to working and counter electrodes the internal Pt voltage probe is centered internally at a known depth within the electrolyte and between corresponding electrodes.
出版年1996
报告类型Technical Report
语种英语
国家美国
来源学科分类30 DIRECT ENERGY CONVERSION ; 36 MATERIALS SCIENCE ; SOLID ELECTROLYTE FUEL CELLS ; ELECTROCHEMISTRY ; LANTHANUM OXIDES ; ELECTRICAL PROPERTIES ; STRONTIUM OXIDES ; MANGANESE OXIDES ; ENERGY LOSSES ; ELECTRODES ; MICROSTRUCTURE ; PROBES ; CALCINATION ; TEMPERATURE DEPENDENCE ; SINTERING ; CATHODES
URLhttp://www.osti.gov/scitech/servlets/purl/460199
资源类型科技报告
条目标识符http://119.78.100.177/qdio/handle/2XILL650/266877
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GB/T 7714
Huebner, W.,Reed, D.M.,Anderson, H.U. [Univ. of Missouri, Rolla, MO . Structure{leftrightarrow}property relationships in solid oxide fuel cells,1996.
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