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DOI | 10.2172/460199 |
报告编号 | CONF-961107--Absts. |
来源ID | OSTI_ID: 460199 |
Structure{leftrightarrow}property relationships in solid oxide fuel cells | |
Huebner, W.; Reed, D.M.; Anderson, H.U. [Univ. of Missouri, Rolla, MO (United States)] | |
英文摘要 | The electrode reactions are a major cause of the energy losses in SOFC`s, and limit their use to higher temperatures, typically 800-1000{degrees}C. The electrode reactions have received much attention aimed at better understanding the electrode kinetics and mechanisms, but are still very primitive in their basic understanding. The electrode microstructure and its corresponding reactivity has commonly been studied by DC and AC impedance techniques. A common method of examining electrode reactions employs surface-mounted reference electrodes, although this technique often limits the experiment to examination of one electrode. In this study a new technique has been developed of utilizing a Pt voltage probe placed internally into the electrolyte to measure the IN and impedance spectra of both electrodes operating under cell conditions. Unlike surface mounted electrodes which need to be concerned with distance and dimensions of reference electrodes with respect to working and counter electrodes the internal Pt voltage probe is centered internally at a known depth within the electrolyte and between corresponding electrodes. |
出版年 | 1996 |
报告类型 | Technical Report |
语种 | 英语 |
国家 | 美国 |
来源学科分类 | 30 DIRECT ENERGY CONVERSION ; 36 MATERIALS SCIENCE ; SOLID ELECTROLYTE FUEL CELLS ; ELECTROCHEMISTRY ; LANTHANUM OXIDES ; ELECTRICAL PROPERTIES ; STRONTIUM OXIDES ; MANGANESE OXIDES ; ENERGY LOSSES ; ELECTRODES ; MICROSTRUCTURE ; PROBES ; CALCINATION ; TEMPERATURE DEPENDENCE ; SINTERING ; CATHODES |
URL | http://www.osti.gov/scitech/servlets/purl/460199 |
资源类型 | 科技报告 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/266877 |
推荐引用方式 GB/T 7714 | Huebner, W.,Reed, D.M.,Anderson, H.U. [Univ. of Missouri, Rolla, MO . Structure{leftrightarrow}property relationships in solid oxide fuel cells,1996. |
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