Arid
云南萝芙木花新吲哚生物碱
其他题名Novel Indole Alkaloid from the Flowers of Rauvolfia yunnanensis
汪海波; 刘锡葵
来源期刊高等学校化学学报
ISSN0251-0790
出版年2010
卷号31期号:10页码:2005-2009
中文摘要从云南萝芙木(Rauvolfia yunnanensis Tsiang)花乙酸乙酯提取物中分离得到9个化合物(其中4个为吲哚类生物碱),即(18Z)-11-Methoxypicrinine(1), Caberoline(2),11-Methoxystrictamine(3)和Strictamine(4),以及Russulamide(5), Ursolic acid(6), Urs-12(13)-en-3alpha-yl acetate(7),beta-Amyryl nonanoate(8)和beta-Sitosterol(9);采用UV,IR,MS和1D,2D NMR方法对化合物的结构进行了鉴定,其中化合物1为新吲哚生物碱,化合物5,7和8系首次从该植物中分离得到,但未得到利血平和育亨宾
英文摘要Rauvolfia yunnanensis Tsiang are commonly used as a folklore herb to treat hypertension, snake bites, and insanity in the southwest of China, and an important industrial raw material of reserpine. The phytochemical constituents of the rhizome of it have been investigated intensively. Reserpine and yohimbine are two effective biological activities compounds isolated from the rhizome of Rauvolfia yunnanensis. But the wild resources of it reduced gradually in recent years, thus we have introduced and cultivated it to the arid hot valley region of Yunnan, China, and investigated the chemical constituents variety of it for the sustainable utilization. In the present work, the chemical constituents of the flowers of R.yunnanensis have been investigated for extending the utilizable efficiency of resources. The dried flowers powder(1.0 kg) of R.yunnanensis was extracted with 95% EtOH(10 L * 6,48 h each) at room temperature, and then extracted successively with EtOAc(1 L * 6).The EtOAc portion(50 g) led to the isolation of nine compounds by column chromatography(silica, alumina and Sephadex LH-20 gel) methods. Their structures were identified as(18Z)-11-methoxypicrinine(1), caberoline(2),11-methoxystrictamine(3), strictamine(4), russulamide(5), ursolic acid(6), urs-12(13)-en-3alpha-yl acetate(7),beta-amyryl nonanoate(8) and beta-sitosterol(9) by spectral analysis(UV,IR,MS and 1D,2D NMR), respectively. Among them, compound 1 is a new indole alkaloids, compounds 5,7 and 8 are firstly isolated from it. But reserpine and yohimbine haven’t been isolated
中文关键词云南萝芙木 ; 吲哚生物碱
英文关键词(18Z)-11-Methoxypicrinine Russulamide Rauvolfia yunnanensis Indole alkaloid (18Z)-11-Methoxypicrinine Russulamide
语种中文
国家中国
收录类别CSCD
WOS类目CHEMISTRY ORGANIC
WOS研究方向Chemistry
CSCD记录号CSCD:4054883
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/225199
作者单位中国科学院昆明植物研究所, 植物化学与西部植物资源持续利用国家重点实验室, 昆明, 云南 650204, 中国
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GB/T 7714
汪海波,刘锡葵. 云南萝芙木花新吲哚生物碱[J],2010,31(10):2005-2009.
APA 汪海波,&刘锡葵.(2010).云南萝芙木花新吲哚生物碱.高等学校化学学报,31(10),2005-2009.
MLA 汪海波,et al."云南萝芙木花新吲哚生物碱".高等学校化学学报 31.10(2010):2005-2009.
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