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DOI10.1007/s10450-018-9990-x
Comparison of adsorption affinity of anionic and cationic polyacrylamides for montmorillonite surface in the presence of chromium(VI) ions
Wisniewska, Malgorzata1; Fijalkowska, Gracja1; Szewczuk-Karpisz, Katarzyna2; Urban, Teresa1; Nosal-Wiercinska, Agnieszka3; Wojcik, Grzegorz4
通讯作者Wisniewska, Malgorzata
来源期刊ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
ISSN0929-5607
EISSN1572-8757
出版年2019
卷号25期号:1页码:41-50
英文摘要Erosion, which is considered to be global problem, is the process of soil environment degradation due to the impact of wind (soil blowing, deflation) and water (soil washing, deep erosion). This leads to destruction of its structure, nutrients removal and finally bedrock exposition and desertification. One of the ways to prevent this phenomenon is the soil conditioners usage. These substances, also called soil flocculants, are macromolecular compounds which contribute to the reinforcement of soil structure as a result of its adsorption on the mineral surface. The soil conditioners commonly used in agriculture is ionic polyacrylamide (PAM)both anionic and cationic. These macromolecular substances affect soil surface properties and adsorption behaviour of substances present in the environmentnutrients, organic molecules and also hazardous compounds as well as toxic heavy metals (i.e. chromium(VI) ions). The aim of this study was to investigate the impact of solution pH, type of ionic groups in the polyacrylamide macromolecules and chromium(VI) ion concentration on the adsorption mechanism of Cr(VI) and PAM on the montmorillonite surface. The adsorption and electrokinetic properties of the montmorilloniteAN PAM or CT PAM/Cr(VI) systems were examined by means of spectrophotometry, potentiometric titration, SEM, XRD and DRS methods. It was shown that in the adsorbed layer composed of PAM-Cr(VI) complexes reduction of Cr(VI) to Cr(III) takes place.
英文关键词Montmorillonite Ionic polyacrylamide PAM adsorption Cr(VI) reduction PAM-Cr(VI) complexes Intercalation
类型Article
语种英语
国家Poland
开放获取类型hybrid
收录类别SCI-E
WOS记录号WOS:000456130200004
WOS关键词AQUEOUS-SOLUTION ; HEAVY-METALS ; SOIL ; WATER ; INFILTRATION ; FLOCCULATION ; KAOLINITE ; STABILITY ; TOXICITY ; SORPTION
WOS类目Chemistry, Physical ; Engineering, Chemical
WOS研究方向Chemistry ; Engineering
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/213873
作者单位1.Marie Curie Sklodowska Univ, Fac Chem, Dept Radiochem & Colloids Chem, M Curie Sklodowska Sq 3, PL-20031 Lublin, Poland;
2.Polish Acad Sci, Inst Agrophys, Doswiadczalna St 4, PL-20290 Lublin, Poland;
3.Marie Curie Sklodowska Univ, Fac Chem, Dept Analyt Chem & Instrumental Anal, M Curie Sklodowska Sq 3, PL-20031 Lublin, Poland;
4.Marie Curie Sklodowska Univ, Fac Chem, Dept Inorgan Chem, M Curie Sklodowska Sq 3, PL-20031 Lublin, Poland
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Wisniewska, Malgorzata,Fijalkowska, Gracja,Szewczuk-Karpisz, Katarzyna,et al. Comparison of adsorption affinity of anionic and cationic polyacrylamides for montmorillonite surface in the presence of chromium(VI) ions[J],2019,25(1):41-50.
APA Wisniewska, Malgorzata,Fijalkowska, Gracja,Szewczuk-Karpisz, Katarzyna,Urban, Teresa,Nosal-Wiercinska, Agnieszka,&Wojcik, Grzegorz.(2019).Comparison of adsorption affinity of anionic and cationic polyacrylamides for montmorillonite surface in the presence of chromium(VI) ions.ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY,25(1),41-50.
MLA Wisniewska, Malgorzata,et al."Comparison of adsorption affinity of anionic and cationic polyacrylamides for montmorillonite surface in the presence of chromium(VI) ions".ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY 25.1(2019):41-50.
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