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Storm water harvesting and storage has been employed for nearly a hundred years, and using storm water to recharge aquifers is one of the most important ways to relieve water scarcity in arid and semi-arid regions. However, it cannot be widely adopted because of clogging problems. The risk of chemical clogging is mostly associated with iron oxyhydroxide precipitation; anhydrous ferric oxide (HFO) clogging remains a problem in many wellfields. This paper investigates Fe(III) clogging levels at three flow velocities (Darcy velocities, 0.46, 1.62 and 4.55 m/d). The results indicate that clogging increases with flow velocity, and is mostly affected by the first 0-3 cm of the column. The highest water velocity caused full clogging in 35 h, whereas the lowest took 53 h to reach an stable 60% reduction in hydraulic conductivity. For the high flow velocity, over 90% of the HFO was deposited in the 0-1 cm section. In contrast, the lowest flow velocity deposited only 75% in this section. Fe(III) deposition was used as an approximation for Fe(OH)(3). High flow velocity may promote Fe(OH)(3) flocculent precipitate, thus increasing Fe(III) deposition. The main mechanism for a porous matrix interception of Fe(III) colloidal particles was surface filtration. Thus, the effects of deposition, clogging phenomena, and physicochemical mechanisms, are more significant at higher velocities.