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DOI | 10.1016/j.talanta.2017.08.071 |
Chemometric optimization of the extraction and derivatization of parabens for their determination in water samples by rotating-disk sorptive extraction and gas chromatography mass spectrometry | |
Becerra-Herrera, Mercedes; Miranda, Valentina; Arismendi, Daniel; Richter, Pablo | |
通讯作者 | Becerra-Herrera, Mercedes ; Richter, Pablo |
来源期刊 | TALANTA
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ISSN | 0039-9140 |
EISSN | 1873-3573 |
出版年 | 2018 |
卷号 | 176页码:551-557 |
英文摘要 | A combination of rotating disk sorptive extraction (RDSE) using Oasis (R) HLB as the sorbent phase and gas chromatography mass spectrometry (GC-MS) has been performed for the determination of four of the most widely used parabens: methylparaben, ethylparaben, propylparaben and n-butylparaben. The extraction and derivatization of the analytes in water samples were optimized by using factorial (screening) and Doehlert designs, thus reducing the number of analyses with the concomitant reduction of time, reagents, waste, samples and cost. Thus, a RDSE method using 20 mL of sample was performed. The disk was rotated at 2900 rpm for 70 min at room temperature. After a desorption step and evaporation of solvent, a derivatization method using 5 mu L of N-methyl-N-(trimethylsilyl)trifluoroacetamide (MSTFA) for 15 min at room temperature was used previously to inject the final extract into GC-MS. The detection limits and precision (%RSD) were lower than 0.05 mu g L-1 and 9.7% for the studied compounds, respectively. Recoveries were studied using effluent samples of a wastewater treatment plant (WWTP), with values higher than 80% being obtained. The applicability and reliability of this methodology were confirmed through the analysis of tap water and influents from Santiago, Chile, with concentration values ranging from 0.57 to 0.83 mu g L-1 in influents. The main advantage of the present RDSE method is that it is significantly faster than its counterpart by SBSE and requires a considerable lower volume of derivatizing agent. |
英文关键词 | Rotating-disk sorptive extraction (RDSE) Parabens Chemometric GC-MS Water samples |
类型 | Article |
语种 | 英语 |
国家 | Chile |
收录类别 | SCI-E |
WOS记录号 | WOS:000412610100069 |
WOS关键词 | ENDOCRINE-DISRUPTING COMPOUNDS ; HALOGENATED BY-PRODUCTS ; SOLID-PHASE EXTRACTION ; P-HYDROXYBENZOIC ACID ; HUMAN BREAST-TUMORS ; WASTE-WATER ; CHLORINATED DERIVATIVES ; METHYL-TRICLOSAN ; RISK-ASSESSMENT ; TRACE ANALYSIS |
WOS类目 | Chemistry, Analytical |
WOS研究方向 | Chemistry |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/213414 |
作者单位 | Univ Chile, Fac Chem & Pharmaceut Sci, Dept Inorgan & Analyt Chem, POB 233, Santiago, Chile |
推荐引用方式 GB/T 7714 | Becerra-Herrera, Mercedes,Miranda, Valentina,Arismendi, Daniel,et al. Chemometric optimization of the extraction and derivatization of parabens for their determination in water samples by rotating-disk sorptive extraction and gas chromatography mass spectrometry[J],2018,176:551-557. |
APA | Becerra-Herrera, Mercedes,Miranda, Valentina,Arismendi, Daniel,&Richter, Pablo.(2018).Chemometric optimization of the extraction and derivatization of parabens for their determination in water samples by rotating-disk sorptive extraction and gas chromatography mass spectrometry.TALANTA,176,551-557. |
MLA | Becerra-Herrera, Mercedes,et al."Chemometric optimization of the extraction and derivatization of parabens for their determination in water samples by rotating-disk sorptive extraction and gas chromatography mass spectrometry".TALANTA 176(2018):551-557. |
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