Arid
DOI10.1016/j.scitotenv.2017.10.049
Trace metal(loid) mobility in waste deposits and soils around Chadak mining area, Uzbekistan
Kodirov, Obidjon1; Kersten, Michael2; Shukurov, Nosir1; Martin Peinado, Francisco Jose3
通讯作者Martin Peinado, Francisco Jose
来源期刊SCIENCE OF THE TOTAL ENVIRONMENT
ISSN0048-9697
EISSN1879-1026
出版年2018
卷号622页码:1658-1667
英文摘要

The assessment of potential trace metal(loid) contamination in tailing dumps and soils was characterized in the Chadak mining area (Uzbekistan). Concentrations of trace elements (V, Cr, Co, Ni, Cu, Zn, As, Cd, Sb, Pb) were determined by X-ray fluorescence analysis and compared with background and intervention values (IV). The concentrations of As, Zn, Sb, and Pb were higher in the abandoned than in the active tailing dump, ranging from 42-1689 mg/kg for As, 73-332 mg/kg for Zn, 14-1507 mg/kg for Sb, and 27-386 mg/kg for Pb. Selective extractions were applied in order to assess the mobility and availability of trace metal(loid)s in samples. Oxyanion-forming elements such as As and Sb were immobilized by Fe oxides, although to some extent also extractable with acetic acid and soluble-in-water forms were detected, indicating potential bioavailability that can impose a potential toxicity risk for the environment. Selective extractions data also showed that Zn and Pb were relatively immobile, although in higher contamination sites significant amounts of these elements were also extractable with acetic acid. In tailing materials Zn and Pb mobility were negatively correlated by the cation-exchange capacity (CEC) and clay content, indicating the importance of these factors in the reduction of the potential toxicity for these elements. Total concentration of As, Sb, and Pb were also negatively correlated with soil pH, indicating that the oxidation process of sulphide tailings and thus the generation of acidic conditions may lead to release of contaminants over time. However, due to the calcium carbonate content, the acid neutralization capacity of the tailings is not yet exhausted and contaminant concentrations in soil-pore water are still relatively low. The results of our investigation suggest that environmental risk associated with these wastes in semi-arid climate is therefore not a short-term problem but rather requires constant monitoring and additional ecotoxicological studies. (c) 2017 Elsevier B.V. All rights reserved.


英文关键词Sulphide tailings Metal(loid) pollution Chemical fractionation
类型Article
语种英语
国家Uzbekistan ; Germany ; Spain
收录类别SCI-E
WOS记录号WOS:000426349000161
WOS关键词SEQUENTIAL EXTRACTION PROCEDURES ; HEAVY-METALS ; MINE TAILINGS ; CONTAMINATED SOIL ; MAJOR ELEMENTS ; SEWAGE-SLUDGE ; ANTIMONY ; CU ; SEDIMENTS ; BEHAVIOR
WOS类目Environmental Sciences
WOS研究方向Environmental Sciences & Ecology
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/212938
作者单位1.Acad Sci Uzbek, Inst Geol & Geophys, Olimlar 49, Tashkent 100041, Uzbekistan;
2.Johannes Gutenberg Univ Mainz, Geosci Inst, D-55099 Mainz, Germany;
3.Univ Granada, Dept Soil Sci, Fac Sci, Campus Fuentenueva S-N, Granada 18002, Spain
推荐引用方式
GB/T 7714
Kodirov, Obidjon,Kersten, Michael,Shukurov, Nosir,et al. Trace metal(loid) mobility in waste deposits and soils around Chadak mining area, Uzbekistan[J],2018,622:1658-1667.
APA Kodirov, Obidjon,Kersten, Michael,Shukurov, Nosir,&Martin Peinado, Francisco Jose.(2018).Trace metal(loid) mobility in waste deposits and soils around Chadak mining area, Uzbekistan.SCIENCE OF THE TOTAL ENVIRONMENT,622,1658-1667.
MLA Kodirov, Obidjon,et al."Trace metal(loid) mobility in waste deposits and soils around Chadak mining area, Uzbekistan".SCIENCE OF THE TOTAL ENVIRONMENT 622(2018):1658-1667.
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