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The late-stage basanite (similar to 12-1 Ma) of the NNW-SSE extending Gharyan Cenozoic volcanics (Northern West Libya) contains numerous fresh lherzolite xenoliths. These xenoliths display magmatic protogranular and porphyroclastic textures. Chemistry of olivine (forsterite content -90-91, NiO = 0.26-0.39 wt %), orthopyroxene (Mg# = 0.91-0.92, Cr# = 0.03-0.07, Al2O3 = 3.64-4.43 wt %), clinopyroxene ((Wo(45.59-48.61), En(45.89-48.80), Fs(4.47-5.81)), Mg# = 0.82-0.92, Al2O3 = 5.14-6.58 wt % and Cr2O3 = 0.5-0.95 wt %) and spinel (hercynite-picotite-Al-rich chromite spinels with Cr# = 0.08-0.11) refer to the fertile nature of Gharyan peridotites. Mantle source region was close to the primitive composition with low degrees of melting and depletion in melt (1.5% in average). However, it underwent metasomatism as illustrated by formation of secondary clinopyroxene (Wo(37.96-44.77), En(47.44-54.18), Fs(7.59-8.03)) with high contents of Na2O, and enrichment of the Al-spinel in TiO2. The estimated pre-eruptive temperature ranges from 1066 to 837 degrees C. Despite the Gharyan peridotite is similar to mantle components in many districts in Saharan belt of North Africa, it represents juvenile mantle source with minor refractory residues. This compositional heterogeneity is mainly attributed to the local effect of the interaction of the Gharyan mantle with the host basanite magma that may be related to the Cenozoic rifting of the Pan-African basement.