Arid
DOI10.1177/0959683618777075
Growth of desert varnish on petroglyphs from Jubbah and Shuwaymis, Ha’il region, Saudi Arabia
Macholdt, Dorothea S.1; Al-Amri, Abdullah M.2; Tuffaha, Husam T.2; Jochum, Klaus Peter1; Andreae, Meinrat O.1,2,3
通讯作者Macholdt, Dorothea S.
来源期刊HOLOCENE
ISSN0959-6836
EISSN1477-0911
出版年2018
卷号28期号:9页码:1495-1511
英文摘要

Petroglyphs, engraved throughout the Holocene into rock varnish coatings on sandstone, were investigated in the Ha’il region of northwestern Saudi Arabia, at Jabal Yatib, Jubbah, and Shuwaymis. The rock art has been created by removing the black varnish coating and thereby exposing the light sandstone underneath. With time, the varnish, a natural manganese (Mn)-rich coating, grows back. To study the rate of regrowth, we made 234 measurements by portable X-ray fluorescence (pXRF) on intact varnish and engraved petroglyphs. Since many petroglyphs can be assigned to a specific time period, a relationship between their ages and the Mn surface densities (D-Mn) of the regrown material could be derived. This relationship was improved by normalizing the D-Mn in the petroglyphs with the D-Mn of adjacent intact varnish. In turn, we used this relationship to assign a chronologic context to petroglyphs of unknown ages. Following the removal of the varnish by the artist and prior to the beginning of Mn oxyhydroxide regrowth, a thin Fe-rich film forms on the underlying rock. This initial Fe oxyhydroxide deposit may act as catalyst for subsequent fast Mn oxidation. After a few decades of relatively rapid growth, the regrowth of the Mn-rich varnish slows down to about 0.017 mu g cm(-2) a(-1) Mn, corresponding to about 0.012% a(-1) Mn of the intact varnish density, or about 1.2 nm a(-1), presumably due to a change of the catalytic process. Our results suggest that petroglyphs were engraved almost continuously since the pre-Neolithic period, and that rock varnish growth seems to proceed roughly linear, without detectable influences of the regional Holocene climatic changes.


英文关键词manganese oxyhydroxides Neolithic period portable XRF rock art rock varnish varnish growth mechanisms
类型Article
语种英语
国家Germany ; Saudi Arabia ; USA
收录类别SCI-E ; SSCI
WOS记录号WOS:000443315700010
WOS关键词ROCK-VARNISH ; MANGANESE-OXIDE ; EARLY HOLOCENE ; CLIMATE-CHANGE ; ART ; OCCUPATION ; OXIDATION ; SURFACES ; DUST
WOS类目Geography, Physical ; Geosciences, Multidisciplinary
WOS研究方向Physical Geography ; Geology
来源机构King Saud University
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/209831
作者单位1.Max Planck Inst Chem, POB 3060, D-55020 Mainz, Germany;
2.King Saud Univ, Geol & Geophys Dept, Riyadh, Saudi Arabia;
3.Univ Calif San Diego, Scripps Inst Oceanog, La Jolla, CA 92093 USA
推荐引用方式
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Macholdt, Dorothea S.,Al-Amri, Abdullah M.,Tuffaha, Husam T.,等. Growth of desert varnish on petroglyphs from Jubbah and Shuwaymis, Ha’il region, Saudi Arabia[J]. King Saud University,2018,28(9):1495-1511.
APA Macholdt, Dorothea S.,Al-Amri, Abdullah M.,Tuffaha, Husam T.,Jochum, Klaus Peter,&Andreae, Meinrat O..(2018).Growth of desert varnish on petroglyphs from Jubbah and Shuwaymis, Ha’il region, Saudi Arabia.HOLOCENE,28(9),1495-1511.
MLA Macholdt, Dorothea S.,et al."Growth of desert varnish on petroglyphs from Jubbah and Shuwaymis, Ha’il region, Saudi Arabia".HOLOCENE 28.9(2018):1495-1511.
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