Arid
DOI10.7503/cjcu20170837
Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies
Qu Xingxing; Dai Yuyu; Li Weijun; Ouyang Mi; Zhang Cheng
通讯作者Zhang Cheng
来源期刊CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
出版年2018
卷号39期号:8页码:1699-1706
英文摘要

The central phenyl and biphenyl groups were introduced into the N-positions of two thiophene-carbazole structures to form the desired 9,9’-(1,4-phenylene)bis[3,6-di-2-thienyl]-9H-carbazole(BTCPh) and 9,9’-[1,1’-biphenyl]-4,4’-diylbis [3,6-di-2-thienyl-9H-carbazole (BTCBPh) , respectively. The obtained BTCPh and BTCBPh were electrochemically polymerized to generate the corresponding polymers , poly 9,9’-(1,4-phenylene)bis[3,6-di-2-thienyl]-9H-carbazole(pBTCPh) and poly 9,9’-[1,1’-biphenyl]-4,4’-diylbis[3,6-di-2-thienyl]-9H-carbazole(pBTCBPh) , which might possess the cross-linked structure. The polymers were investigated by different character methods , such as cyclic voltammetry , multi-current step , ultra-violet visible near infrared absorption spectrum, scanning electron microscope and so on. The results showed that both of pBTCPh and pBTCBPh polymers exhibited excellent electrochromic properties with similar color changes , high optical contrast and good electrochemical cycle stability. And pBTCPh polymer film showed the faster color switching speed than pBTCBPh , which was ascribed to the possible more uniform stack structure in pBTCPh film. The uniform stack structure was beneficial to the fast ion inserting/deserting behavior in the electrochromic process.


英文关键词Thiophene-carbazole derivative Electrochromic color Packing structure Response time
类型Article
语种中文
国家Peoples R China
收录类别SCI-E
WOS记录号WOS:000440135100012
WOS关键词LIGHT-EMITTING-DIODES ; POLYMERS ; HOLE ; POLY(2,7-CARBAZOLE) ; BEHAVIOR ; FILMS
WOS类目Chemistry, Multidisciplinary
WOS研究方向Chemistry
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/208389
作者单位Zhejiang Univ Technol, Coll Chem Engn, Int Sci & Tech Cooperat Base Energy Mat & Applica, Hangzhou 310014, Zhejiang, Peoples R China
推荐引用方式
GB/T 7714
Qu Xingxing,Dai Yuyu,Li Weijun,et al. Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies[J],2018,39(8):1699-1706.
APA Qu Xingxing,Dai Yuyu,Li Weijun,Ouyang Mi,&Zhang Cheng.(2018).Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,39(8),1699-1706.
MLA Qu Xingxing,et al."Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 39.8(2018):1699-1706.
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