Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.7503/cjcu20170837 |
Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies | |
Qu Xingxing; Dai Yuyu; Li Weijun; Ouyang Mi; Zhang Cheng | |
通讯作者 | Zhang Cheng |
来源期刊 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
![]() |
ISSN | 0251-0790 |
出版年 | 2018 |
卷号 | 39期号:8页码:1699-1706 |
英文摘要 | The central phenyl and biphenyl groups were introduced into the N-positions of two thiophene-carbazole structures to form the desired 9,9’-(1,4-phenylene)bis[3,6-di-2-thienyl]-9H-carbazole(BTCPh) and 9,9’-[1,1’-biphenyl]-4,4’-diylbis [3,6-di-2-thienyl-9H-carbazole (BTCBPh) , respectively. The obtained BTCPh and BTCBPh were electrochemically polymerized to generate the corresponding polymers , poly 9,9’-(1,4-phenylene)bis[3,6-di-2-thienyl]-9H-carbazole(pBTCPh) and poly 9,9’-[1,1’-biphenyl]-4,4’-diylbis[3,6-di-2-thienyl]-9H-carbazole(pBTCBPh) , which might possess the cross-linked structure. The polymers were investigated by different character methods , such as cyclic voltammetry , multi-current step , ultra-violet visible near infrared absorption spectrum, scanning electron microscope and so on. The results showed that both of pBTCPh and pBTCBPh polymers exhibited excellent electrochromic properties with similar color changes , high optical contrast and good electrochemical cycle stability. And pBTCPh polymer film showed the faster color switching speed than pBTCBPh , which was ascribed to the possible more uniform stack structure in pBTCPh film. The uniform stack structure was beneficial to the fast ion inserting/deserting behavior in the electrochromic process. |
英文关键词 | Thiophene-carbazole derivative Electrochromic color Packing structure Response time |
类型 | Article |
语种 | 中文 |
国家 | Peoples R China |
收录类别 | SCI-E |
WOS记录号 | WOS:000440135100012 |
WOS关键词 | LIGHT-EMITTING-DIODES ; POLYMERS ; HOLE ; POLY(2,7-CARBAZOLE) ; BEHAVIOR ; FILMS |
WOS类目 | Chemistry, Multidisciplinary |
WOS研究方向 | Chemistry |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/208389 |
作者单位 | Zhejiang Univ Technol, Coll Chem Engn, Int Sci & Tech Cooperat Base Energy Mat & Applica, Hangzhou 310014, Zhejiang, Peoples R China |
推荐引用方式 GB/T 7714 | Qu Xingxing,Dai Yuyu,Li Weijun,et al. Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies[J],2018,39(8):1699-1706. |
APA | Qu Xingxing,Dai Yuyu,Li Weijun,Ouyang Mi,&Zhang Cheng.(2018).Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,39(8),1699-1706. |
MLA | Qu Xingxing,et al."Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 39.8(2018):1699-1706. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。