Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1021/acssuschemeng.8b01433 |
Production of High-Density Renewable Aviation Fuel from Arid Land Crop | |
Yang, Xiaokun1; Uddin, M. Helal1; Zhou, Xinpei1; Neupane, Bishnu2; Miller, Glenn C.2; Coronella, Charles J.1; Poulson, Simon R.3; Lin, Hongfei4 | |
通讯作者 | Lin, Hongfei |
来源期刊 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING |
ISSN | 2168-0485 |
出版年 | 2018 |
卷号 | 6期号:8页码:10108-10119 |
英文摘要 | Grindelia squarrosa biocrude is a promising feedstock for producing high-density cycloalkane fuels for high-performance aircraft due to the branched tricyclic nature of its primary diterpenoid component, grindelic acid. Herein we designed a novel biphasic tandem catalytic process (biTCP) for the conversion of Grindelia squarrosa biocrude into high-density aviation fuels with a superior carbon atom efficiency. The systematic experimental studies provided valuable insights into the effects of process conditions. The detailed speciation was carried out with the complementary chemical analysis techniques. Under the optimum conditions, a similar to 90% carbon yield of aviation fuel components was produced from the Grindelia squarrosa biocrude. Multistep tandem reactions, including cyclic ether ring opening, dehydration, hydrogenation, and decarboxylation were carried out in the "one-pot" biTCP. The detailed catalytic reaction mechanism is discussed. A continuous process was designed integrating the extraction of biocrude and its conversion to dense jet fuels using biTCP. The techno-economic analysis has been performed, and in its current state, the proposed process is expected to deliver price-competitive high-density aviation fuel products. |
英文关键词 | High-density aviation fuel Biphasic process Tandem catalysis Cycloalkane Terpenoid Palladium |
类型 | Article |
语种 | 英语 |
国家 | USA |
收录类别 | SCI-E |
WOS记录号 | WOS:000441475500065 |
WOS关键词 | AQUEOUS-PHASE HYDRODEOXYGENATION ; HIGH-QUALITY DIESEL ; RANGE ALKANES ; CATALYTIC CONVERSION ; LIQUID ALKANES ; MULTIFUNCTIONAL CATALYST ; LIGNOCELLULOSIC BIOMASS ; BIFUNCTIONAL CATALYSTS ; EFFICIENT CONVERSION ; BIODIESEL PRODUCTION |
WOS类目 | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/207153 |
作者单位 | 1.Univ Nevada, Dept Chem & Mat Engn, 1664 North Virginia St, Reno, NV 89557 USA; 2.Univ Nevada, Dept Nat Resources & Environm Sci, 1664 North Virginia St, Reno, NV 89557 USA; 3.Univ Nevada, Dept Geol Sci & Engn, 1664 North Virginia St, Reno, NV 89557 USA; 4.Washington State Univ, Gene & Linda Voiland Sch Chem Engn & Bioengn, Wegner Hall 105,1505 Stadium Way, Pullman, WA 99164 USA |
推荐引用方式 GB/T 7714 | Yang, Xiaokun,Uddin, M. Helal,Zhou, Xinpei,et al. Production of High-Density Renewable Aviation Fuel from Arid Land Crop[J],2018,6(8):10108-10119. |
APA | Yang, Xiaokun.,Uddin, M. Helal.,Zhou, Xinpei.,Neupane, Bishnu.,Miller, Glenn C..,...&Lin, Hongfei.(2018).Production of High-Density Renewable Aviation Fuel from Arid Land Crop.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(8),10108-10119. |
MLA | Yang, Xiaokun,et al."Production of High-Density Renewable Aviation Fuel from Arid Land Crop".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.8(2018):10108-10119. |
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