Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1039/c7ra08366a |
Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments | |
Gu, Wenjun1,3; Li, Yongjie2; Tang, Mingjin1; Jia, Xiaohong1,3; Ding, Xiang1; Bi, Xinhui1; Wang, Xinming1,4 | |
通讯作者 | Tang, Mingjin |
来源期刊 | RSC ADVANCES
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ISSN | 2046-2069 |
出版年 | 2017 |
卷号 | 7期号:74页码:46866-46873 |
英文摘要 | The existence of liquid water is a prerequisite for habitability. Deliquescence of perchlorates under subsaturated conditions has been proposed to explain the occurrence of liquid water in some hyperarid environments on the earth and on the Mars. However, the amount of liquid water associated with perchlorates under different conditions is not well understood yet. In this work, we have measured deliquescence relative humidity (DRH) of three perchlorates at different temperatures from 278 to 303 K. DRH decreases from (42.8 +/- 0.6)% at 278 K to (40.5 +/- 0.5)% at 303 K for Mg(ClO4)(2)center dot 6H(2)O, and from (18.5 +/- 0.5)% at 278 K to (15.5 +/- 0.5)% at 303 K for Ca(ClO4)(2)center dot 4H(2)O; in contrast, deliquescence of KClO4 did not occur even when RH (relative humidity) was increased to 95%. In addition, we have determined the amount of water taken up by Ca(ClO4)(2)center dot 4H(2)O and Mg(ClO4)(2)center dot 6H(2)O as a function of RH (0-90%) and temperatures (278-298 K). It is found that when both salts are deliquesced, more water (similar to 10% on average) is associated with Mg(ClO4)(2)center dot 6H(2)O than Ca(ClO4)(2)center dot 4H(2)O on the per mole ClO4- base. Overall, this work would significantly improve our knowledge in hygroscopicity of perchlorates, and thus may provide fundamental insights into the hydrologic cycles in some hyperarid regions on the earth and on the Mars. |
类型 | Article |
语种 | 英语 |
国家 | Peoples R China |
收录类别 | SCI-E |
WOS记录号 | WOS:000412451500040 |
WOS关键词 | ATACAMA DESERT ; PHASE-TRANSITIONS ; AQUEOUS-SOLUTIONS ; UNITED-STATES ; LANDING SITE ; MARS ; DELIQUESCENCE ; TEMPERATURE ; SPECTROSCOPY ; NACLO4 |
WOS类目 | Chemistry, Multidisciplinary |
WOS研究方向 | Chemistry |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/202134 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Key Lab Environm Protect & Resources Ut, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China; 2.Univ Macau, Fac Sci & Technol, Department Civil & Environm Engn, Ave Univ, Taipa, Macau, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 4.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China |
推荐引用方式 GB/T 7714 | Gu, Wenjun,Li, Yongjie,Tang, Mingjin,et al. Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments[J],2017,7(74):46866-46873. |
APA | Gu, Wenjun.,Li, Yongjie.,Tang, Mingjin.,Jia, Xiaohong.,Ding, Xiang.,...&Wang, Xinming.(2017).Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments.RSC ADVANCES,7(74),46866-46873. |
MLA | Gu, Wenjun,et al."Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments".RSC ADVANCES 7.74(2017):46866-46873. |
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