Arid
DOI10.1039/c7ra08366a
Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments
Gu, Wenjun1,3; Li, Yongjie2; Tang, Mingjin1; Jia, Xiaohong1,3; Ding, Xiang1; Bi, Xinhui1; Wang, Xinming1,4
通讯作者Tang, Mingjin
来源期刊RSC ADVANCES
ISSN2046-2069
出版年2017
卷号7期号:74页码:46866-46873
英文摘要

The existence of liquid water is a prerequisite for habitability. Deliquescence of perchlorates under subsaturated conditions has been proposed to explain the occurrence of liquid water in some hyperarid environments on the earth and on the Mars. However, the amount of liquid water associated with perchlorates under different conditions is not well understood yet. In this work, we have measured deliquescence relative humidity (DRH) of three perchlorates at different temperatures from 278 to 303 K. DRH decreases from (42.8 +/- 0.6)% at 278 K to (40.5 +/- 0.5)% at 303 K for Mg(ClO4)(2)center dot 6H(2)O, and from (18.5 +/- 0.5)% at 278 K to (15.5 +/- 0.5)% at 303 K for Ca(ClO4)(2)center dot 4H(2)O; in contrast, deliquescence of KClO4 did not occur even when RH (relative humidity) was increased to 95%. In addition, we have determined the amount of water taken up by Ca(ClO4)(2)center dot 4H(2)O and Mg(ClO4)(2)center dot 6H(2)O as a function of RH (0-90%) and temperatures (278-298 K). It is found that when both salts are deliquesced, more water (similar to 10% on average) is associated with Mg(ClO4)(2)center dot 6H(2)O than Ca(ClO4)(2)center dot 4H(2)O on the per mole ClO4- base. Overall, this work would significantly improve our knowledge in hygroscopicity of perchlorates, and thus may provide fundamental insights into the hydrologic cycles in some hyperarid regions on the earth and on the Mars.


类型Article
语种英语
国家Peoples R China
收录类别SCI-E
WOS记录号WOS:000412451500040
WOS关键词ATACAMA DESERT ; PHASE-TRANSITIONS ; AQUEOUS-SOLUTIONS ; UNITED-STATES ; LANDING SITE ; MARS ; DELIQUESCENCE ; TEMPERATURE ; SPECTROSCOPY ; NACLO4
WOS类目Chemistry, Multidisciplinary
WOS研究方向Chemistry
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/202134
作者单位1.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Key Lab Environm Protect & Resources Ut, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China;
2.Univ Macau, Fac Sci & Technol, Department Civil & Environm Engn, Ave Univ, Taipa, Macau, Peoples R China;
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China;
4.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China
推荐引用方式
GB/T 7714
Gu, Wenjun,Li, Yongjie,Tang, Mingjin,et al. Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments[J],2017,7(74):46866-46873.
APA Gu, Wenjun.,Li, Yongjie.,Tang, Mingjin.,Jia, Xiaohong.,Ding, Xiang.,...&Wang, Xinming.(2017).Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments.RSC ADVANCES,7(74),46866-46873.
MLA Gu, Wenjun,et al."Water uptake and hygroscopicity of perchlorates and implications for the existence of liquid water in some hyperarid environments".RSC ADVANCES 7.74(2017):46866-46873.
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