Arid
DOI10.1039/c7cp04898j
The role of phase separation and related topography in the exceptional ice-nucleating ability of alkali feldspars
Whale, Thomas F.1; Holden, Mark A.1,2; Kulak, Alexander N.2; Kim, Yi-Yeoun2; Meldrum, Fiona C.2; Christenson, Hugo K.3; Murray, Benjamin J.1
通讯作者Whale, Thomas F.
来源期刊PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN1463-9076
EISSN1463-9084
出版年2017
卷号19期号:46页码:31186-31193
英文摘要

Our understanding of crystal nucleation is a limiting factor in many fields, not least in the atmospheric sciences. It was recently found that feldspar, a component of airborne desert dust, plays a dominant role in triggering ice formation in clouds, but the origin of this effect was unclear. By investigating the structure/property relationships of a wide range of feldspars, we demonstrate that alkali feldspars with certain microtextures, related to phase separation into Na and K-rich regions, show exceptional icenucleating abilities in supercooled water. We found no correlation between ice-nucleating efficiency and the crystal structures or the chemical compositions of these active feldspars, which suggests that specific topographical features associated with these microtextures are key in the activity of these feldspars. That topography likely acts to promote ice nucleation, improves our understanding of ice formation in clouds, and may also enable the design and manufacture of bespoke nucleating materials for uses such as cloud seeding and cryopreservation.


类型Article
语种英语
国家England
收录类别SCI-E
WOS记录号WOS:000416425400020
WOS关键词CRYSTAL NUCLEATION ; IMMERSION MODE ; ACTIVE-SITES ; HETEROGENEOUS NUCLEATION ; ATMOSPHERIC PARTICLES ; SURFACE-ROUGHNESS ; ORGANIC-CRYSTALS ; K-RICH ; CRYSTALLIZATION ; AEROSOLS
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS研究方向Chemistry ; Physics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/201448
作者单位1.Univ Leeds, Sch Earth & Environm, Leeds LS2 9JT, W Yorkshire, England;
2.Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England;
3.Univ Leeds, Sch Phys & Astron, Leeds LS2 9JT, W Yorkshire, England
推荐引用方式
GB/T 7714
Whale, Thomas F.,Holden, Mark A.,Kulak, Alexander N.,et al. The role of phase separation and related topography in the exceptional ice-nucleating ability of alkali feldspars[J],2017,19(46):31186-31193.
APA Whale, Thomas F..,Holden, Mark A..,Kulak, Alexander N..,Kim, Yi-Yeoun.,Meldrum, Fiona C..,...&Murray, Benjamin J..(2017).The role of phase separation and related topography in the exceptional ice-nucleating ability of alkali feldspars.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,19(46),31186-31193.
MLA Whale, Thomas F.,et al."The role of phase separation and related topography in the exceptional ice-nucleating ability of alkali feldspars".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 19.46(2017):31186-31193.
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