Arid
DOI10.1016/j.gca.2016.10.024
Investigating the hydrological significance of stalagmite geochemistry (Mg, Sr) using Sr isotope and particulate element records across the Late Glacial-to-Holocene transition
Belli, R.1,5; Borsato, A.1; Frisia, S.1; Drysdale, R.2,3; Maas, R.4; Greig, A.4
通讯作者Belli, R.
来源期刊GEOCHIMICA ET COSMOCHIMICA ACTA
ISSN0016-7037
EISSN1872-9533
出版年2017
卷号199页码:247-263
英文摘要

The trace element and Sr isotope records in two coeval stalagmites characterized by different growth rates and flow regimes at Savi cave (Grotta Savi, NE Italy) reveal different sources and incorporation mechanisms for Mg and Sr. Mg is sourced primarily from dissolved cave host rock while particulate Mg derived from soil plays a subordinate role. The presence of particulate-borne Mg is inferred from the co-variation of Mg and particle-associated elements (Th, Al and Mn) which are preferentially concentrated in open columnar calcite layers. Variation in Mg concentrations corrected for particleinfluenced components, the Mg-c parameter, is controlled by water-rock interaction, with higher and lower Mg-c during dry and wet phases, respectively. This is thought to reflect incongruent dissolution of Mg-rich phases. Correction of Sr concentrations for contributions from airborne exogenic Sr, based on Sr-87/Sr-86 ratios, yields the bedrock-only contribution (Sr-c). Sr-c variation in stalagmite calcite is influenced by speleothem growth rate and by variation of the calcite-water Sr partitioning in wet and dry phases, and only to a minor extent by incongruent dissolution of Mg-rich phases. Concentration profiles for Mg-c and Sr-cg (corrected for growth rate effects) show inverse correlations and are inferred to show hydrological significance which is captured in a hydrological index, HI. We suggest HI provides robust information on water-rock interaction related to hydrological changes and can be utilized in both wet and semi-arid environments, provided the corrections for soil Mg and exogenic Sr can be applied with confidence. Application of the HI index allows correction of Grotta Savi oxygen isotope data, to yield a delta O-18(c) time series that shows when changes in moisture sources and atmospheric reorganization, or changes in moisture amount, were significant. This is especially evident during the Younger Dryas (YD). The Savi record supports the concept of a two-phase YD, marked by an increase of moisture and stronger impact of Adriatic and Mediterranean Sea influences over the northern Adriatic region from 12.3 ka onwards. Then, a large-scale atmospheric reorganization and gradual northward shift of the Polar Front caused a progressive reduction of sea influence over the region from 12.1 ka, supporting the concept of a hemispheric change. (C) 2016 Elsevier Ltd. All rights reserved.


英文关键词Hydrological changes Strontium Magnesium Thorium Sr isotopes Stalagmites Lateglacial Holocene Younger Dryas
类型Article
语种英语
国家Australia ; France ; Italy
收录类别SCI-E
WOS记录号WOS:000393125500017
WOS关键词TRACE-ELEMENT ; YOUNGER DRYAS ; NORTHERN-HEMISPHERE ; LAST DEGLACIATION ; CALCITE FABRICS ; ORGANIC-MATTER ; SPELEOTHEM ; CLIMATE ; CAVE ; VARIABILITY
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/199186
作者单位1.Univ Newcastle, Sch Environm & Life Sci, Callaghan, Vic 2308, Australia;
2.Univ Melbourne, Sch Geog, Melbourne, Vic 3010, Australia;
3.Univ Savoie Mont Blanc, Lab EDYTEM UMR CNRS 5204, F-73376 Le Bourget Du Lac, France;
4.Univ Melbourne, Sch Earth Sci, Melbourne, Vic 3010, Australia;
5.Univ Trento, Ctr Integrat Biol, I-38123 Povo, Italy
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Belli, R.,Borsato, A.,Frisia, S.,et al. Investigating the hydrological significance of stalagmite geochemistry (Mg, Sr) using Sr isotope and particulate element records across the Late Glacial-to-Holocene transition[J],2017,199:247-263.
APA Belli, R.,Borsato, A.,Frisia, S.,Drysdale, R.,Maas, R.,&Greig, A..(2017).Investigating the hydrological significance of stalagmite geochemistry (Mg, Sr) using Sr isotope and particulate element records across the Late Glacial-to-Holocene transition.GEOCHIMICA ET COSMOCHIMICA ACTA,199,247-263.
MLA Belli, R.,et al."Investigating the hydrological significance of stalagmite geochemistry (Mg, Sr) using Sr isotope and particulate element records across the Late Glacial-to-Holocene transition".GEOCHIMICA ET COSMOCHIMICA ACTA 199(2017):247-263.
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