Arid
DOI10.1021/acs.est.7b00588
Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust
Park, Jiyeon; Jang, Myoseon; Yu, Zechen
通讯作者Jang, Myoseon
来源期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN0013-936X
EISSN1520-5851
出版年2017
卷号51期号:17页码:9605-9613
英文摘要

The impact of authentic mineral dust particles sourced from the Gobi Desert (GDD) on the kinetic uptake coefficient of SO2 was studied under varying environments (humidity, O-3, and NOx) using both an indoor chamber and an outdoor chamber. There was a significant increase in the kinetic uptake coefficient of SO2 (gamma(2-)(SO4,light)) for GDD particles under UV light compared to the value (gamma(2-)(SO4,dark)) under dark conditions at various relative humidities (RH) ranging from 20% to 80%. In both the presence and the absence of O-3 and NOx, gamma(2-)(SO4,light) and gamma(2-)(SO4,dark),dark greatly increased with increasing RH. The resulting, gamma(2-)(SO4,light) of GDD particles was also compared to that of Arizona Test Dust (ATD) particles. The gamma(2-)(SO4,light) values of GDD were 2 to 2.5 times greater than those of ATD for all RH levels. To understand the phototatalytic act of dust particles, both GDD and ATD were characterized for the metal element composition of fresh particles, the aerosol acidity of aged particles, and the hygroscopic properties of both fresh and aged particles. We conclude that the difference in the formation of sulfate between GDD and ATD particles is regulated mainly by the quantity of the semiconductive metals in dust particles and partially by hygroscopic properties.


类型Article
语种英语
国家USA
收录类别SCI-E
WOS记录号WOS:000410255800021
WOS关键词SULFUR-DIOXIDE ; SAHARAN DUST ; DESERT DUST ; NITRIC-ACID ; HYGROSCOPIC PROPERTIES ; CALCIUM-CARBONATE ; HYDROGEN-PEROXIDE ; KNUDSEN CELL ; FLOW TUBE ; AEROSOL
WOS类目Engineering, Environmental ; Environmental Sciences
WOS研究方向Engineering ; Environmental Sciences & Ecology
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/198772
作者单位Univ Florida, Dept Environm Engn Sci, POB 116450, Gainesville, FL 32611 USA
推荐引用方式
GB/T 7714
Park, Jiyeon,Jang, Myoseon,Yu, Zechen. Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust[J],2017,51(17):9605-9613.
APA Park, Jiyeon,Jang, Myoseon,&Yu, Zechen.(2017).Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust.ENVIRONMENTAL SCIENCE & TECHNOLOGY,51(17),9605-9613.
MLA Park, Jiyeon,et al."Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust".ENVIRONMENTAL SCIENCE & TECHNOLOGY 51.17(2017):9605-9613.
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