Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1021/acs.est.7b00588 |
Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust | |
Park, Jiyeon; Jang, Myoseon; Yu, Zechen | |
通讯作者 | Jang, Myoseon |
来源期刊 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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ISSN | 0013-936X |
EISSN | 1520-5851 |
出版年 | 2017 |
卷号 | 51期号:17页码:9605-9613 |
英文摘要 | The impact of authentic mineral dust particles sourced from the Gobi Desert (GDD) on the kinetic uptake coefficient of SO2 was studied under varying environments (humidity, O-3, and NOx) using both an indoor chamber and an outdoor chamber. There was a significant increase in the kinetic uptake coefficient of SO2 (gamma(2-)(SO4,light)) for GDD particles under UV light compared to the value (gamma(2-)(SO4,dark)) under dark conditions at various relative humidities (RH) ranging from 20% to 80%. In both the presence and the absence of O-3 and NOx, gamma(2-)(SO4,light) and gamma(2-)(SO4,dark),dark greatly increased with increasing RH. The resulting, gamma(2-)(SO4,light) of GDD particles was also compared to that of Arizona Test Dust (ATD) particles. The gamma(2-)(SO4,light) values of GDD were 2 to 2.5 times greater than those of ATD for all RH levels. To understand the phototatalytic act of dust particles, both GDD and ATD were characterized for the metal element composition of fresh particles, the aerosol acidity of aged particles, and the hygroscopic properties of both fresh and aged particles. We conclude that the difference in the formation of sulfate between GDD and ATD particles is regulated mainly by the quantity of the semiconductive metals in dust particles and partially by hygroscopic properties. |
类型 | Article |
语种 | 英语 |
国家 | USA |
收录类别 | SCI-E |
WOS记录号 | WOS:000410255800021 |
WOS关键词 | SULFUR-DIOXIDE ; SAHARAN DUST ; DESERT DUST ; NITRIC-ACID ; HYGROSCOPIC PROPERTIES ; CALCIUM-CARBONATE ; HYDROGEN-PEROXIDE ; KNUDSEN CELL ; FLOW TUBE ; AEROSOL |
WOS类目 | Engineering, Environmental ; Environmental Sciences |
WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/198772 |
作者单位 | Univ Florida, Dept Environm Engn Sci, POB 116450, Gainesville, FL 32611 USA |
推荐引用方式 GB/T 7714 | Park, Jiyeon,Jang, Myoseon,Yu, Zechen. Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust[J],2017,51(17):9605-9613. |
APA | Park, Jiyeon,Jang, Myoseon,&Yu, Zechen.(2017).Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust.ENVIRONMENTAL SCIENCE & TECHNOLOGY,51(17),9605-9613. |
MLA | Park, Jiyeon,et al."Heterogeneous Photo-oxidation of SO2 in the Presence of Two Different Mineral Dust Particles: Gobi and Arizona Dust".ENVIRONMENTAL SCIENCE & TECHNOLOGY 51.17(2017):9605-9613. |
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