Arid
DOI10.1016/j.epsl.2017.04.014
Lithium isotopes in speleothems: Temperature-controlled variation in silicate weathering during glacial cycles
von Strandmann, Philip A. E. Pogge1,2,3; Vaks, Anton3,4; Bar-Matthews, Miryam4; Ayalon, Avner4; Jacob, Ezekiel3; Henderson, Gideon M.3
通讯作者von Strandmann, Philip A. E. Pogge
来源期刊EARTH AND PLANETARY SCIENCE LETTERS
ISSN0012-821X
EISSN1385-013X
出版年2017
卷号469页码:64-74
英文摘要

Terrestrial chemical weathering of silicate minerals is a fundamental component of the global cycle of carbon and other elements. Past changes in temperature, rainfall, ice cover, sea-level and physical erosion are thought to affect weathering but the relative impact of these controls through time remains poorly constrained. This problem could be addressed if the nature of past weathering could be constrained at individual sites. In this study, we investigate the use of speleothems as local recorders of the silicate weathering proxy, Li isotopes. We analysed delta Li-7 and [Li] in speleothems that formed during the past 200 ka in two well-studied Israeli caves (Soreq and Tzavoa), as well as in the overlying soils and rocks. Leaching and mass balance of these soils and rocks show that Li is dominantly sourced from weathering of the overlying aeolian silicate soils. Speleothem delta 7Li values are ubiquitously higher during glacials (similar to 23%) than during interglacials(similar to 10%(0)), implying more congruent silicate weathering during interglacials (where "congruent" means a high ratio of primary mineral dissolution to secondary mineral formation). These records provide information on the processes controlling weathering in Israel. Consideration of possible processes causing this change of weathering congruency indicates a primary role for temperature, with higher temperatures causing more congruent weathering (lower delta Li-7(speieo)). The strong relationship observed between speleothem delta Li-7 and climate at these locations suggests that Li isotopes may be a powerful tool with which to understand the local controls on weathering at other sites, and could be used to assess the distribution of weathering changes accompanying climate change, such as that of Pleistocene glacial cycles. (C) 2017 Elsevier B.V. All rights reserved.


英文关键词weathering glaciation climate lithium isotopes temperature
类型Article
语种英语
国家England ; Israel
收录类别SCI-E
WOS记录号WOS:000402444700006
WOS关键词EASTERN MEDITERRANEAN REGION ; SOREQ CAVE ; NEGEV DESERT ; INTERGLACIAL VARIATIONS ; SECONDARY MINERALS ; ARABIAN DESERT ; GRAIN-SIZE ; CLIMATE ; LI ; DUST
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
来源机构University of London ; University of Oxford
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/198333
作者单位1.UCL, Inst Earth & Planetary Sci, London Geochem & Isotope Ctr LOGIC, Gower St, London WC1E 6BT, England;
2.Birkbeck Univ London, Gower St, London WC1E 6BT, England;
3.Univ Oxford, Dept Earth Sci, South Parks Rd, Oxford, England;
4.Geol Survey Israel, 30 Malkhey Israel St, IL-9550161 Jerusalem, Israel
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von Strandmann, Philip A. E. Pogge,Vaks, Anton,Bar-Matthews, Miryam,et al. Lithium isotopes in speleothems: Temperature-controlled variation in silicate weathering during glacial cycles[J]. University of London, University of Oxford,2017,469:64-74.
APA von Strandmann, Philip A. E. Pogge,Vaks, Anton,Bar-Matthews, Miryam,Ayalon, Avner,Jacob, Ezekiel,&Henderson, Gideon M..(2017).Lithium isotopes in speleothems: Temperature-controlled variation in silicate weathering during glacial cycles.EARTH AND PLANETARY SCIENCE LETTERS,469,64-74.
MLA von Strandmann, Philip A. E. Pogge,et al."Lithium isotopes in speleothems: Temperature-controlled variation in silicate weathering during glacial cycles".EARTH AND PLANETARY SCIENCE LETTERS 469(2017):64-74.
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