Arid
DOI10.1016/j.sedgeo.2016.05.002
Geochemistry of the Miocene oil shale (Hancili Formation) in the Cankiri-Corum Basin, Central Turkey: Implications for Paleoclimate conditions, source-area weathering, provenance and tectonic setting
Moradi, A. Vosoughi1; Sari, A.2; Akkaya, P.1
通讯作者Moradi, A. Vosoughi
来源期刊SEDIMENTARY GEOLOGY
ISSN0037-0738
EISSN1879-0968
出版年2016
卷号341页码:289-303
英文摘要

The geochemistry of oil shale units of Hancili Formation in the cankiri-corum Basin (Central Turkey) was studied using various chemical analyses. The mineralogical composition of the samples were preliminarily investigated using Pearson’s correlation coefficients of selected elements, indicating that the samples contain abundant clay minerals as well as K-feldspar and carbonate. The K2O/Al2O3 and SiO2/Al2O3 ratios indicate that the major proportion of clay minerals is composed of smectite. Si, Al, Ti, K, Na, and Fe reside in clay minerals, while Ca, Mg, and Mn are mostly associated with carbonates (e.g., calcite and dolomite) and phosphorous (P) is present as apatite. The total REE content of the oil shale range from 19 to 113 ppm. The chondrite-normalized patterns of the oil shale show LREE enrichments, HREE deficits, negative Eu anomalies and negligible Ce anomalies. In general, major, trace and rare earth element abundances suggest that the studied oil shale in the Canlari-corum Basin are mainly from the intermediate rocks, mixed with small amounts of basic rocks, and that their source rocks are mostly deposited in the continental collision setting. The REE geochemistry of the oil shale suggests that these samples were derived from a consistent terrigenous source and the Eu anomaly was inherited from the source rocks. The paleoclimate index (C-value), varies between 0.07 and 1.22 reflecting a generally semi-arid to humid conditions. In addition, Rb/Sr (similar to 022) and Sr/Cu (similar to 9.09) ratios support the idea that warm and humid conditions prevailed during deposition of the Hancili Formation. Sr/Ba ratios (0.54-3.7) of the studied samples suggest a paleoenvironment with variable salinity. The co-variation among this factor and paleoclimate indicators suggest that variations in climatic conditions exerted a primary control on salinity. The substantially low C-value and Rb/Sr ratio and significantly high ratios of Sr/Cu and Sr/Ba and also elevated carbonate content of four samples indicate that these samples were deposited during hot and arid periods and that the paleoclimate controlled the terrigenous sediment flux to the lake basin. The chemical index of alteration (CIA), A-CN-K ternary diagram, and high Th/U ratios indicate that the parent rocks of the oil shale experienced moderate chemical weathering (steady state). (C) 2016 Elsevier B.V. All rights reserved.


英文关键词Geochemistry Tectonic setting Provenance Paleoclimate Paleosalinity Oil shale
类型Article
语种英语
国家Turkey
收录类别SCI-E
WOS记录号WOS:000381540200020
WOS关键词RARE-EARTH-ELEMENTS ; NEOTETHYAN SUTURE ZONE ; FINE-GRAINED SEDIMENTS ; MAJOR-ELEMENT ; SILICICLASTIC SEDIMENTS ; CRUSTAL EVOLUTION ; CENTRAL ANATOLIA ; PLATE-TECTONICS ; ARCHEAN SHALES ; SOUTH-AFRICA
WOS类目Geology
WOS研究方向Geology
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/196380
作者单位1.Ankara Univ, Grad Sch Nat & Appl Sci, TR-06110 Ankara, Turkey;
2.Ankara Univ, Dept Geol Engn, TR-06100 Ankara, Turkey
推荐引用方式
GB/T 7714
Moradi, A. Vosoughi,Sari, A.,Akkaya, P.. Geochemistry of the Miocene oil shale (Hancili Formation) in the Cankiri-Corum Basin, Central Turkey: Implications for Paleoclimate conditions, source-area weathering, provenance and tectonic setting[J],2016,341:289-303.
APA Moradi, A. Vosoughi,Sari, A.,&Akkaya, P..(2016).Geochemistry of the Miocene oil shale (Hancili Formation) in the Cankiri-Corum Basin, Central Turkey: Implications for Paleoclimate conditions, source-area weathering, provenance and tectonic setting.SEDIMENTARY GEOLOGY,341,289-303.
MLA Moradi, A. Vosoughi,et al."Geochemistry of the Miocene oil shale (Hancili Formation) in the Cankiri-Corum Basin, Central Turkey: Implications for Paleoclimate conditions, source-area weathering, provenance and tectonic setting".SEDIMENTARY GEOLOGY 341(2016):289-303.
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