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Urbanization has increased heat in the urban environment, with many consequences for human health and wellbeing. Managing climate change in part through increasing vegetation is desired by many cities to mitigate current and future heat related issues. However, little information is available on what influences the current effectiveness and availability of vegetation for local cooling. In this study, we identified the variation in the interacting relationships among vegetation (normalized difference vegetation index), socioeconomic status (neighborhood income), elevation and land surface temperature (LST) to identify how vegetation based surface cooling services change throughout the pronounced coastal to desert climate gradient of the Los Angeles, CA metropolitan region, a megacity of >18 million residents. A key challenge for understanding variation in vegetation as a climate change adaptation tool spanning neighborhood to megacity scales is developing new "big data" analytical tools. We used structural equation modeling (SEM) to quantify the interacting relationships among socio-economic status data obtained from government census data, elevation and new LST and vegetation data obtained from an airborne imaging campaign conducted in 2013 for the urban and suburban areas across a series of fifteen climate zones. Vegetation systematically increased in cooling effectiveness from 6.06 to 31.77 degrees with increasing distance from the coast. Vegetation and neighborhood income were positively correlated throughout all climate zones with a peak in the relationship occurring near 25 km from the coast. Because of the interaction between these two relationships, we also found that higher income neighborhoods were cooler and that this effect peaked at about 30 km from the coast. These results show the availability and effectiveness of vegetation on the local climate varies tremendously throughout the Los Angeles, CA metropolitan area. Further, using the more inland climate zones as future analogs for more coastal zones, suggests that in the warmer climate conditions projected for the region the effectiveness of vegetation for regional cooling may increase thus acting as a localized negative feedback mechanism. (C) 2016 Elsevier B.V. All rights reserved.