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DOI | 10.1039/c5ra22668f |
Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure | |
Hu, Xiaonan1; Shi, Liyi2; Zhang, Dengsong1; Zhao, Xin1; Huang, Lei1 | |
通讯作者 | Zhang, Dengsong ; Huang, Lei |
来源期刊 | RSC ADVANCES
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ISSN | 2046-2069 |
出版年 | 2016 |
卷号 | 6期号:17页码:14192-14198 |
英文摘要 | In this work, we developed a facile, green and low-cost strategy for the controllable synthesis of birnessite-type MnO2 (Bir-MnO2) nanosheets assembled in a "desert rose"-like 3D hierarchical nanostructure and proposed a two-step growth route, namely photolysis and followed by auto-catalytic decomposition of KMnO4. Bir-MnO2 nanosheets were first obtained under the irradiation of a light source and acted as seeds for further decomposition of the excess MnO4- in the dark. The sizes of the Bir-MnO2 3D hierarchical nanostructures could be readily controlled by varying the concentration of KMnO4, the light source and the pH value. Furthermore, Bir-MnO2 nanosheets on CNTs were successfully fabricated utilizing the same strategy without the addition of any surfactants or organic templates. It is anticipated that the fabrication of Bir-MnO2 based nanostructures and composites could be beneficial from this universal method. |
类型 | Article |
语种 | 英语 |
国家 | Peoples R China |
收录类别 | SCI-E |
WOS记录号 | WOS:000369639400072 |
WOS关键词 | MANGANESE OXIDE ; HIGH-PERFORMANCE ; SUPERCAPACITOR ELECTRODE ; HYDROTHERMAL SYNTHESIS ; AQUEOUS-SOLUTION ; NANOSHEETS ; DEGRADATION ; COMPOSITES ; MORPHOLOGY ; NANOTUBES |
WOS类目 | Chemistry, Multidisciplinary |
WOS研究方向 | Chemistry |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/196142 |
作者单位 | 1.Shanghai Univ, Res Ctr Nano Sci & Technol, Shanghai 200444, Peoples R China; 2.Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, Xiaonan,Shi, Liyi,Zhang, Dengsong,et al. Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure[J],2016,6(17):14192-14198. |
APA | Hu, Xiaonan,Shi, Liyi,Zhang, Dengsong,Zhao, Xin,&Huang, Lei.(2016).Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure.RSC ADVANCES,6(17),14192-14198. |
MLA | Hu, Xiaonan,et al."Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure".RSC ADVANCES 6.17(2016):14192-14198. |
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