Arid
DOI10.1039/c5ra22668f
Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure
Hu, Xiaonan1; Shi, Liyi2; Zhang, Dengsong1; Zhao, Xin1; Huang, Lei1
通讯作者Zhang, Dengsong ; Huang, Lei
来源期刊RSC ADVANCES
ISSN2046-2069
出版年2016
卷号6期号:17页码:14192-14198
英文摘要

In this work, we developed a facile, green and low-cost strategy for the controllable synthesis of birnessite-type MnO2 (Bir-MnO2) nanosheets assembled in a "desert rose"-like 3D hierarchical nanostructure and proposed a two-step growth route, namely photolysis and followed by auto-catalytic decomposition of KMnO4. Bir-MnO2 nanosheets were first obtained under the irradiation of a light source and acted as seeds for further decomposition of the excess MnO4- in the dark. The sizes of the Bir-MnO2 3D hierarchical nanostructures could be readily controlled by varying the concentration of KMnO4, the light source and the pH value. Furthermore, Bir-MnO2 nanosheets on CNTs were successfully fabricated utilizing the same strategy without the addition of any surfactants or organic templates. It is anticipated that the fabrication of Bir-MnO2 based nanostructures and composites could be beneficial from this universal method.


类型Article
语种英语
国家Peoples R China
收录类别SCI-E
WOS记录号WOS:000369639400072
WOS关键词MANGANESE OXIDE ; HIGH-PERFORMANCE ; SUPERCAPACITOR ELECTRODE ; HYDROTHERMAL SYNTHESIS ; AQUEOUS-SOLUTION ; NANOSHEETS ; DEGRADATION ; COMPOSITES ; MORPHOLOGY ; NANOTUBES
WOS类目Chemistry, Multidisciplinary
WOS研究方向Chemistry
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/196142
作者单位1.Shanghai Univ, Res Ctr Nano Sci & Technol, Shanghai 200444, Peoples R China;
2.Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China
推荐引用方式
GB/T 7714
Hu, Xiaonan,Shi, Liyi,Zhang, Dengsong,et al. Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure[J],2016,6(17):14192-14198.
APA Hu, Xiaonan,Shi, Liyi,Zhang, Dengsong,Zhao, Xin,&Huang, Lei.(2016).Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure.RSC ADVANCES,6(17),14192-14198.
MLA Hu, Xiaonan,et al."Accelerating the decomposition of KMnO4 by photolysis and auto-catalysis: a green approach to synthesize a layered birnessite-type MnO2 assembled hierarchical nanostructure".RSC ADVANCES 6.17(2016):14192-14198.
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