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The absolute radiometric calibration of a satellite sensor is the critical factor that ensures the usefulness of the acquired data for quantitative applications on remote sensing. This work presents the results of the first cross-calibration of the sensor on board the Sistema Satelital de Observacion de la Tierra (SSOT) Chilean satellite or Air Force Satellite FASat-C. RapidEye-MSI was chosen as the reference sensor, and a simultaneous Nadir Overpass Approach (SNO) was applied. The biases caused by differences in the spectral responses of both instruments were compensated through an adjustment factor derived from EO-1 Hyperion data. Through this method, the variations affecting the radiometric response of New AstroSat Optical Modular Instrument (NAOMI-1), have been corrected based on collections over the Frenchman Flat calibration site. The results of a preliminary evaluation of the pre-flight and updated coefficients have shown a significant improvement in the accuracy of at-sensor radiances and TOA reflectances: an average agreement of 2.63% (RMSE) was achieved for the multispectral bands of both instruments. This research will provide a basis for the continuity of calibration and validation tasks of future Chilean space missions.