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DOI10.1016/j.polymer.2016.07.034
A simple and fast formation of biodegradable poly(urethane-urea) hydrogel with high water content and good mechanical property
Xue, Sasa1,2; Pei, Danfeng1; Jiang, Wei3; Mu, Youbing1; Wan, Xiaobo1
通讯作者Mu, Youbing ; Wan, Xiaobo
来源期刊POLYMER
ISSN0032-3861
EISSN1873-2291
出版年2016
卷号99页码:340-348
英文摘要

The synthesis of biodegradable hydrogels with both good mechanical properties and high water content is still a great challenge. In this study, a simple and scalable strategy for the preparation of a biodegradable polyurethane prepolymer composed of isocyanate terminated linear polyethylene glycol (L-PEG) and isocyanate terminated three-armed poly(L-lactic acid) (T-PLLA) is described. When mixed with water, the prepolymer forms a poly(urethane-urea) hydrogel in few minutes. The effect of the molecular weight and the feeding ratio of L-PEG and T-PLLA on the mechanical property of the poly(urethane-urea) hydrogel is discussed. The resulting hydrogel shows good mechanical properties with high tensile strength (up to 108 KPa) and recorded elongation rate (4500%), while maintaining high water content (up to 91% mass ratio). Meanwhile, the maximum water retaining capacity of the hydrogel can be up to 38 times of PU prepolymer (in mass), which is equal to 97.4% water content. Its degradation property is analyzed by the loss of tensile strength and cross section morphology through SEM with time. Such a low cost and biodegradable poly(urethane-urea) hydrogel, which combines fast hydrogel formation, high water content and good mechanical properties, might be used as potential candidates for applications in agrological field, such as sand fixing in desertification control. (C) 2016 Elsevier Ltd. All rights reserved.


英文关键词Poly(urethane-urea) hydrogel Polylactic acid Biodegradation
类型Article
语种英语
国家Peoples R China
收录类别SCI-E
WOS记录号WOS:000383885000038
WOS关键词ENVIRONMENT-SENSITIVE HYDROGELS ; POLYURETHANE HYDROGELS ; DRUG-DELIVERY ; POLY(ETHYLENE GLYCOL) ; PH SENSITIVITY ; POLYMERS ; RELEASE ; COPOLYMERS ; BEHAVIORS ; ADHESIVE
WOS类目Polymer Science
WOS研究方向Polymer Science
来源机构南京大学
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/195711
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Shandong, Peoples R China;
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China;
3.Nanjing Univ, Sch Environm, Natl Engn Res Ctr Organ Pollut Control & Resource, State Key Lab Pollut & Resource Reuse, 22 Hankou Rd, Nanjing 210093, Jiangsu, Peoples R China
推荐引用方式
GB/T 7714
Xue, Sasa,Pei, Danfeng,Jiang, Wei,et al. A simple and fast formation of biodegradable poly(urethane-urea) hydrogel with high water content and good mechanical property[J]. 南京大学,2016,99:340-348.
APA Xue, Sasa,Pei, Danfeng,Jiang, Wei,Mu, Youbing,&Wan, Xiaobo.(2016).A simple and fast formation of biodegradable poly(urethane-urea) hydrogel with high water content and good mechanical property.POLYMER,99,340-348.
MLA Xue, Sasa,et al."A simple and fast formation of biodegradable poly(urethane-urea) hydrogel with high water content and good mechanical property".POLYMER 99(2016):340-348.
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