Arid
DOI10.1080/10426507.2015.1073279
Synthesis of a fumed silica-supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane
Li, Ji; Zhang, Lei; Li, Tingting; Yang, Chunhui
通讯作者Li, Ji
来源期刊PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN1042-6507
EISSN1563-5325
出版年2016
卷号191期号:5页码:728-733
英文摘要

A novel fumed silica-supported bidentate nitrogen platinum complex vvas conveniently prepared from N-(2-arninoethyl)-3-arninopropyltriethoxysilarie via irrimobilization on fumed silica followed by a reaction with hexachloroplatinic acid. The title complex was systematically characterized arid analyzed by Fourier Transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and specific surface area analysis (BET). The resulting title complex was found to be efficient and stable in catalyzing the hydrosilylation reacti.on of olefins with triethox)fsilane. Furthermore, the polymeric platinum complex could be separated by simple filtration and reused four times without any appreciable loss of catalytic activity


英文关键词Hydrosilylation bidentate nitrogen platinum complex supported catalyst heterogeneous catalysis
类型Article
语种英语
国家Peoples R China
收录类别SCI-E
WOS记录号WOS:000377120600011
WOS关键词EFFICIENT CATALYST ; RECENT PROGRESS ; DOUBLE-BONDS ; HYDROSILATION ; ALKENES ; PHOSPHIRANES ; CONVENIENT ; MECHANISM ; HYDRIDES ; LIGANDS
WOS类目Chemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS研究方向Chemistry
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/195443
作者单位Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China
推荐引用方式
GB/T 7714
Li, Ji,Zhang, Lei,Li, Tingting,et al. Synthesis of a fumed silica-supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane[J],2016,191(5):728-733.
APA Li, Ji,Zhang, Lei,Li, Tingting,&Yang, Chunhui.(2016).Synthesis of a fumed silica-supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane.PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,191(5),728-733.
MLA Li, Ji,et al."Synthesis of a fumed silica-supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane".PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191.5(2016):728-733.
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