Arid
DOI10.1038/nature16956
Condensation on slippery asymmetric bumps
Park, Kyoo-Chul1,2; Kim, Philseok2; Grinthal, Alison1; He, Neil1; Fox, David1; Weaver, James C.2; Aizenberg, Joanna1,2,3
通讯作者Park, Kyoo-Chul ; Aizenberg, Joanna
来源期刊NATURE
ISSN0028-0836
EISSN1476-4687
出版年2016
卷号531期号:7592页码:78-82
英文摘要

Controlling dropwise condensation is fundamental to water-harvesting systems(1-3), desalination(4), thermal power generation(4-8), air conditioning(9), distillation towers(10), and numerous other applications(4,5,11). For any of these, it is essential to design surfaces that enable droplets to grow rapidly and to be shed as quickly as possible(4-7). However, approaches(4-8,10-21) based on microscale, nanoscale or molecular-scale textures suffer from intrinsic tradeoffs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approachbased on principles derived from Namib desert beetles(3,22-24), cacti(25), and pitcher plants(17,26)-that synergistically combines these aspects of condensation and substantially outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle’s bumpy surface geometry in promoting condensation, and using theoretical modelling, we show how to maximize vapour diffusion flux(20,27,28) at the apex of convex millimetric bumps by optimizing the radius of curvature and cross-sectional shape. Integrating this apex geometry with a widening slope, analogous to cactus spines, directly couples facilitated droplet growth with fast directional transport, by creating a free-energy profile that drives the droplet down the slope before its growth rate can decrease. This coupling is further enhanced by a slippery, pitcher-plant-inspired nanocoating that facilitates feedback between coalescence-driven growth and capillary-driven motion on the way down. Bumps that are rationally designed to integrate these mechanisms are able to grow and transport large droplets even against gravity and overcome the effect of an unfavourable temperature gradient. We further observe an unprecedented sixfold-higher exponent of growth rate, faster onset, higher steady-state turnover rate, and a greater volume of water collected compared to other surfaces. We envision that this fundamental understanding and rational design strategy can be applied to a wide range of water-harvesting and phase-change heat-transfer applications.


类型Article
语种英语
国家USA
收录类别SCI-E
WOS记录号WOS:000371211900043
WOS关键词SUPERHYDROPHOBIC SURFACES ; NANOSTRUCTURED SURFACES ; WATER COLLECTION ; DESERT BEETLE ; ENHANCED CONDENSATION ; DROPWISE CONDENSATION ; CAPTURE ; GROWTH ; ENERGY
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/195175
作者单位1.Harvard Univ, John A Paulson Sch Engn & Appl Sci, Cambridge, MA 02138 USA;
2.Harvard Univ, Wyss Inst Biol Inspired Engn, Cambridge, MA 02138 USA;
3.Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
推荐引用方式
GB/T 7714
Park, Kyoo-Chul,Kim, Philseok,Grinthal, Alison,et al. Condensation on slippery asymmetric bumps[J],2016,531(7592):78-82.
APA Park, Kyoo-Chul.,Kim, Philseok.,Grinthal, Alison.,He, Neil.,Fox, David.,...&Aizenberg, Joanna.(2016).Condensation on slippery asymmetric bumps.NATURE,531(7592),78-82.
MLA Park, Kyoo-Chul,et al."Condensation on slippery asymmetric bumps".NATURE 531.7592(2016):78-82.
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