Arid
DOI10.1016/j.gexplo.2016.07.024
Chlorine isotopic constraint on contrastive genesis of representative coastal and inland shallow brine in China
Du, Yao; Ma, Teng1; Chen, Liuzhu; Xiao, Cong; Liu, Cunfu
通讯作者Ma, Teng
来源期刊JOURNAL OF GEOCHEMICAL EXPLORATION
ISSN0375-6742
EISSN1879-1689
出版年2016
卷号170页码:21-29
英文摘要

There are great scientific interests to reveal the shallow brine genesis in different geologic environments and also practical significance for resource production and environmental protection, which have not yet gained much attention, however. This study took shallow Quaternary brine in the coastal plain of Laizhou Bay and salt lake brine/intercrystalline brine in arid inland Qaidam Basin in China as two kinds of representative shallow brines, and comparatively analyzed the Cl stable isotopic signatures, coupled with hydrochemistry and water isotopes, aiming at finding out the salinity origin of shallow brines in the coast and inland basin, and further discussing Cl stable isotopic behavior in actual hydrogeological systems. The results indicated that shallow brine in the coastal zone originated from evaporation and precipitation formerly, and halite dissolution by tidewater or rainwater later, as a result of which, most of shallow brine exhibited enriched Cl isotopic signatures. As a contrast in arid inland basin, superficial brine originated from the dissolution of precipitated salt minerals by river water formerly, and intensive evaporation with subsequent precipitation in basin center later, for which all the brines finally exhibited the depleted Cl isotopic signatures. In addition, diffusion and ion filtration in the coast zone, and inflow of deep oilfield water in inland basin, were proposed as potential processes contributing to respective Cl isotopic signatures. In the coast, Cl-37 are enriched and Br-81 are depleted in most of shallow brines, while all the superficial brine (saline water) samples in arid inland basin exhibit negative delta Cl-37 and positive delta Br-81 values. Precipitation and dissolution of salt minerals were believed to contribute primarily to the contrary isotopic signatures, which would not change the Br isotopic compositions a lot for the solution in which the original Br concentration has been relatively high, which is not the case for Cl isotope, however. (C) 2016 Published by Elsevier B.V.


英文关键词Shallow brine Coast Inland basin Cl isotope China
类型Article
语种英语
国家Peoples R China
收录类别SCI-E
WOS记录号WOS:000386405300003
WOS关键词STABLE CHLORINE ; LAIZHOU BAY ; ENVIRONMENTAL ISOTOPES ; SEDIMENTARY BASIN ; BROMINE ISOTOPES ; NATURAL SAMPLES ; FORMATION WATER ; QAIDAM BASIN ; GROUNDWATER ; EVOLUTION
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/194434
作者单位1.China Univ Geosci, State Key Lab Biogeol & Environm Geol, Wuhan 430074, Peoples R China;
2.China Univ Geosci, Sch Environm Studies, Wuhan 430074, Peoples R China
推荐引用方式
GB/T 7714
Du, Yao,Ma, Teng,Chen, Liuzhu,et al. Chlorine isotopic constraint on contrastive genesis of representative coastal and inland shallow brine in China[J],2016,170:21-29.
APA Du, Yao,Ma, Teng,Chen, Liuzhu,Xiao, Cong,&Liu, Cunfu.(2016).Chlorine isotopic constraint on contrastive genesis of representative coastal and inland shallow brine in China.JOURNAL OF GEOCHEMICAL EXPLORATION,170,21-29.
MLA Du, Yao,et al."Chlorine isotopic constraint on contrastive genesis of representative coastal and inland shallow brine in China".JOURNAL OF GEOCHEMICAL EXPLORATION 170(2016):21-29.
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