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Water demand in islands, focused in agriculture, domestic use and tourism, is usually supplied by groundwater. Thus the information about groundwater distribution is an important issue in islands water resources management. Time Domain Electromagnetic (TDEM) provides underground resistivity distribution at greater depths and is of easier application than other methods. In this study TDEM technique was used for groundwater prospection in two volcanic islands with water supply problems, the islands of Fogo and Santo Antao in the Republic of Cape Verde. The 10 islands of Cape Verde Archipelago, located off the coast of Senegal (W Africa), present a semi-arid climate and thus suffer from irregular and scarce precipitation. In the Island of Fogo 26 TDEM soundings, presenting an area distribution, were performed on the SW flank of the volcanic edifice. These allowed obtaining a 3D model composed of 5 layers parallel to the topographic surface separated by 50 m depth down to -250 m. The results indicate the presence of the water-table at a depth of 150 m in the lower ranges of the W flank of the island, and at >200 m depth in the area above 250 m above sea level (a.s.l.). In the Island of Santo Antao 32 TDEM soundings, distributed along 5 linear profiles, were obtained on the north-eastern half of the island. The profiles are located in two regions exposed to different humidity conditions to the N and S of the main water divide. The northern flank receives the dominant trade winds first and most of the precipitation and, therefore, the water-table is shallower (similar to 50 m depth) than in the S (similar to 100 m depth). Our study demonstrates the applicability and usefulness of the TDEM method for groundwater prospection in high resistivity contexts such as in volcanic islands. (C) 2016 Elsevier B.V. All rights reserved.